| 168134-42-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 168134-42-7
• 化学式: C₂₆H₇₀NdO₂P₃Si₆
• 分子量: 820.515
• InChiKey: BKYUTLPPLIMULP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [NdI₃(THF)_3.5] 、 KP(SiMe3)2 以 四氢呋喃 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Phosphido Complexes of the Lanthanides. Synthesis and x-ray Crystal Structure Determination of a Tris(phosphido) Species of Neodymium: Nd[P(SiMe3)2]3(thf)2

  摘要：

  The reaction of NdI3(thf)(x) (x = 3.5) with 3 equiv of KP(SiMe(3))(2) in tetrahydrofuran has been studied. The X-ray crystal structure determination of Nd[P(SiMe(3))(2)]3-(thf)(2), the first tris(phosphido) complex of the lanthanide element neodymium, is reported. The molecular structure features the pentacoordinate neodymium atom in a slightly distorted trigonal-bipyramidal environment with the phosphido ligands in equatorial and the thf molecules in axial positions.

  DOI：

  10.1021/ic00125a043