Stereochemistry and mechanisms of reactions of dioxygen complexes with organic electrophiles as studied by use of chiral reagents and isotopic labeling
Chemistry of platinum hydrides. Part XXII. Formation of trinuclea cluster complexes from platinum(II) dihydrides containing bulky phosphines
作者:H.C. Clark、A.B. Goel、C.S. Wong
DOI:10.1016/s0020-1693(00)94695-4
日期:1979.1
Abstract Carbon monoxide reacts readily under ambient conditions with platinum(II) dihydrides containing bulky phosphines, PtH2(PR3)2 (where PR3 = Cy3P, Pri3P, But2BunP and ButPh2P) i benzene solution displacing hydrogen as well as one phosphine ligand and giving trinuclear cluster complexes cotaining bridging carbonyl groups. These cluster complexes, which can aloso be preprared by the reactions of
Chemistry of metal diene complexes: a convenient synthesis of selected bis(tertiary phosphine)platinum(0) complexes and their dioxygen platinum(II) adducts