metoprotryne | 3084-58-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: metoprotryne
• 英文别名: 2-methylmercapto-4-(2-methoxyethylamino)-6-isopropylamino-s-triazine；4-N-(2-methoxyethyl)-6-methylsulfanyl-2-N-propan-2-yl-1,3,5-triazine-2,4-diamine
• CAS: 3084-58-0
• 化学式: C₁₀H₁₉N₅OS
• 分子量: 257.36
• InChiKey: ZQHPUPALTSRCNK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  97.3
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  阿特拉津 、 2-Chlor-4.6-bis-<3-methoxy-propylamino>-s-triazin 、 扑灭通 、 2-chloro-4-ethylamino-6-(3-methoxy-n-propylamino)-s-triazine 、 扑草净 、 、 莠灭净 、 扑灭津 、 阿特拉通 、 metoprotryne 、 嗪草酮 生成 西玛津
  参考文献：
  名称：

  6-arylpyrimidines and herbicidal use

  摘要：

  一类6-芳基嘧啶类化合物可用于除草，其一般式为：##STR1## 其中R.sup.2选自氢、卤素、取代或未取代的烷基、卤代烷基、多卤代烷基、卤代烯基、多卤代烯基、卤代炔基、多卤代炔基、烯基、炔基、烷氧基、烷硫基、烷氧羰基烷基、氰基、烷氧基烷基、烷氧羰基、环烷基、芳基烷基、烷基氨基、二烷基氨基或二烷基氨基羰基基团；R.sup.3是烷基、烯基、炔基或卤代烷基基团；R.sup.5是烷基、烯基、炔基、烯炔基或烷氧基烷基基团；R.sup.6是芳基基团（例如芳环）；X是氧或硫。 R.sup.2和R.sup.3可以形成融合的环。

  公开号：

  US05298481A1

文献信息

• Herbicidal-1-(disubstituted carbamoyl or
  申请人：Rohm and Haas Company

  公开号：US05211739A1

  公开（公告）日：1993-05-18

  This invention relates to 1-(disubstituted carbamoyl or thiocarbamoyl)-1,2,4-triazol-3-yl sulfonates and thiosulfonates of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl and cycloalkynyl, or they may together with the nitrogen to which they are attached form an optionally substituted heterocyclic ring, R.sup.3 is an optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl or aromatic heterocyclic group, X and Y are each independently oxygen or sulfur, and the agronomically acceptable acid addition salts and metal complexes thereof, compositions containing these compounds and their uses as herbicides.

  本发明涉及1-(二取代氨基甲酰基或硫氨基甲酰基)-1,2,4-三唑-3-基磺酸盐和硫代磺酸盐的化合物，其化学式为##STR1##其中R.sup.1和R.sup.2各自独立地选自选配取代的烷基、烯基、炔基、环烷基、环烯基和环炔基，或者它们可以与它们附着的氮一起形成选配取代的杂环环，R.sup.3是选配取代的烷基、环烷基、烯基、环烯基、芳香族、芳香基烷基或芳香族杂环基，X和Y各自独立地是氧或硫，以及其农学上可接受的酸加成盐和金属配合物、含有这些化合物的组合物和它们作为除草剂的用途。
• Herbicidal 1-(disubstituted
  申请人：Rohm and Haas Company

  公开号：US05258361A1

  公开（公告）日：1993-11-02

  This invention relates to 1-(disubstituted carbamoyl)-3-(N-arylsulfonamido)-1,2,4-triazoles of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, haloalkyl, alkoxyalkyl and haloalkoxyalkyl, R.sup.3 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, haloalkyl, alkoxyalkyl or haloalkoxyalkyl, Ar is an optionally substituted aryl group, and the agronomically acceptable acid addition salts and metal complexes thereof, compositions containing these compounds and their uses as herbicides.

  本发明涉及式子为##STR1##的1-(二取代氨基甲酰基)-3-(N-芳基磺酰氨基)-1,2,4-三唑类化合物，其中R.sup.1和R.sup.2各自独立选择自烷基、烯基、炔基、环烷基、环烷基烷基、环烯基、环烯基烷基、卤代烷基、烷氧基烷基和卤代烷氧基烷基的群体中的一种；R.sup.3是氢、烷基、烯基、炔基、环烷基、环烷基烷基、环烯基、环烯基烷基、卤代烷基、烷氧基烷基或卤代烷氧基烷基；Ar是可选取代的芳基基团；以及这些化合物的农业上可接受的酸盐和金属络合物、含有这些化合物的组合物以及它们作为除草剂的用途。
• Halopyridyl triazolinone herbicides and herbicidal use thereof
  申请人：Rohm and Haas Company

  公开号：US05733849A1

  公开（公告）日：1998-03-31

  Disclosed are herbicidal halopyridyl triazolinones, herbicidal compositions comprising the halopyridyl triazolinones, and herbicidal use of the compounds and compositions. Such compounds and compositions are useful as both preemergence and postemergence herbicides in a variety of crops.

  本发明涉及除草的卤代吡啶基三唑啉酮，包含该卤代吡啶基三唑啉酮的除草组合物，以及该化合物和组合物的除草用途。这种化合物和组合物在各种农作物中作为早期和后期除草剂都很有用。
• Novel substituted nitrodiphenyl ethers, herbicidal compositions containing them, processes for the preparation thereof and the use thereof for combating weeds
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0020052A1

  公开（公告）日：1980-12-10

  Novel substituted nitrodiphenyl ethers, herbicidal compositions containing them, processes for the preparation thereof and the use thereof for combating weeds. Novel compounds are provided which exhibit activity as herbicides for combating weeds. The novel compounds have the formula: wherein X is hydrogen, halo, trihalomethyl, alkyl, cyano or nitro; X' is hydrogen, halo or trihalomethyl; X2 is trihalomethyl or halo; Y is 0, NH, NR1 or S; R1 and R2 are the same or different and are selected from hydrogen, (C1-C4) alkyl, phenyl and phenyl (C1-C4) alkyl; n is an integer of from 1 to 5; and Z is carboxy, amino, monoalkylamino, or dialkylamino. Also provided are agronomically acceptable salts, esters and amides of a compound of Formula I when Z is carboxy.

  新型取代的硝基二苯醚、含有它们的除草组合物、其制备工艺及其用于除草的用途。 本发明提供了具有除草活性的新型化合物。这些新型化合物的化学式如下 式中 X 是氢、卤素、三卤甲基、烷基、氰基或硝基； X' 是氢、卤素或三卤甲基； X2 是三卤甲基或卤素； Y 是 0、NH、NR1 或 S； R1 和 R2 相同或不同，选自氢、（C1-C4）烷基、苯基和苯基（C1-C4）烷基； n 是 1 至 5 的整数；以及 Z 是羧基、氨基、单烷基氨基或二烷基氨基。 当 Z 为羧基时，还提供农艺学上可接受的式 I 化合物的盐、酯和酰胺。
• Novel heterocyclic substituted benzenes, herbicidal compositions containing them and the use thereof for combating weeds
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0068822A2

  公开（公告）日：1983-01-05

  Compounds of the formula below are disclosed as selective herbicides: where W is a substituted heterocyclic selected from: wherein A is O or S: halo is chloro, bromo or fluoro; R1 and R2 are the same or different radicals seiectea from hydrogen or (C1-C4) alkyl; X is hydrogen or halo: X1 is methylene. O or S; Z is carboxy, alkoxyalkoxy, alkoxycarbonyl. alkoxycarbonylalkoxycarbonyl, alkoxyalkoxycarbonyl, acyloxy, acylalkoxy. cyanoalkoxy, alkylthioalkoxy, alkoxycarbonylalkoxy, alkoxycarbonylalkenyloxy, a 5- to 6-membered heterocyclic, formylalkoxy. haloalkoxy, mononuclear arylcarbonyalkoxy, oxiranylalkoxy, ammo. monoalkyl amino. dialkylamino, hydrazino, monoal- kythydrazino, dialkylhydrazino, acyiamino. alkoxyamino, alkoxycarbonylamino, mono- or dialkylcarbonylamino, N-alkyl-N-al- koxyalkylaminocarbonylamino, haloalkylcarbonylamino, N-alkylsulfonylaminocarbonyl, N-alkylsulfonylamino, monoalkenylamino, dialkenylamino, monoalkynylamino, dialkynylamino, N-alkyl-N-alkenylamino, or N-alkyl-N-alkynylamino: R is hydrogen or (C1-C4)alkyl and R3 ana R4 are the same or different and are selected from hydrogen. (C1-C4)-alkyl, (C3-C5)alkenyl or (C3-C5)alkynyl.

  下式化合物被公开为选择性除草剂： 式中 W 是选自下列化合物的取代杂环： 其中 A 是 O 或 S：卤素是氯、溴或氟；R1 和 R2 是由氢或（C1-C4）烷基分离出来的相同或不同的基；X 是氢或卤素：X1 是亚甲基。O或S；Z是羧基、烷氧基烷氧基、烷氧羰基、烷氧羰基烷氧羰基、烷氧烷氧羰基、酰氧基、酰基烷氧基、氰基烷氧基、烷硫基烷氧基、烷氧羰基烷氧基、烷氧羰基烯氧基、5-6元杂环、甲酰基烷氧基、卤代烷氧基、单核烷氧基。单烷基氨基、二烷基氨基、肼基、单醛基肼基、二烷基肼基、酰氨基、烷氧基氨基、烷氧基羰基烷氧基、烷氧基羰基烯氧基、5 至 6 元杂环、甲酰基烷氧基、卤代烷氧基、单核芳基羰基烷氧基、环氧乙烷烷氧基、酰胺。烷氧基氨基、烷氧基羰基氨基、单烷基或二烷基羰基氨基、N-烷基-N-烷氧基烷基氨基羰基氨基、卤代烷基羰基氨基、N-烷基磺酰基氨基羰基、N-烷基磺酰基氨基、单烯基氨基、二烯基氨基、单炔基氨基、二炔基氨基、N-烷基-N-烯基氨基或 N-烷基-N-炔基氨基：R是氢或(C1-C4)烷基，R3和R4相同或不同，选自氢。(C1-C4)-烷基、(C3-C5)烯基或(C3-C5)炔基。