(C4H9)2Sn(CH3COO)2 * (thioacetamide)2 | 200567-57-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (C4H9)2Sn(CH3COO)2 * (thioacetamide)2
• CAS: 200567-57-3
• 化学式: C₁₆H₃₄N₂O₄S₂Sn
• 分子量: 501.299
• InChiKey: GAHVUUKTHDJXOI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二乙酸二丁基锡 、 硫代乙酰胺 以 丙酮 为溶剂， 以72%的产率得到(C4H9)2Sn(CH3COO)2 * (thioacetamide)2
  参考文献：
  名称：

  Complexes of Some Group IV Metal Halides, Acetate and Organotins with Thioacetamide

  摘要：

  Reactions of silicon tetrachloride, titanium tetrachloride, zirconium tetrachloride, tin tetrachloride, trimethyltin chloride, dibutyltin diacetate and tributyltin chloride with thioacetamide led to the formation of non-ionic and stable complexes of the formula MCl4.(TA)(2) and SnX4.(TA)(2) (where M = Si, Ti, Zr or Sn and X = Cl and CH3, CH3COO and C4H9 or C4H9 and Cl, and TA = thioacetamide). These complexes were characterized by melting/decomposition point determinations, analytical data, conductivity measurements and spectroscopic (UV and IR) studies. An octahedral geometry is proposed for all the complexes and coordination through sulphur is predicted.

  DOI：

  10.1080/00945719708003161