bis(6-acetyl-5-dehydroxy-2-methylbenzo[b]furane)copper(II) monohydrate | 1392418-39-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: bis(6-acetyl-5-dehydroxy-2-methylbenzo[b]furane)copper(II) monohydrate
• CAS: 1392418-39-1
• 化学式: C₂₂H₁₈CuO₆*H₂O
• 分子量: 459.943
• InChiKey: FYNKLSPYNSHAKG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  6-acetyl-5-hydroxy-2-methylbenzo[b]furan 、 水 、 铜 在 Me₄NClO₄ 作用下， 以 乙醇 为溶剂， 生成 bis(6-acetyl-5-dehydroxy-2-methylbenzo[b]furane)copper(II) monohydrate
  参考文献：
  名称：

  Synthesis and structural studies of novel Cu(II) complexes with hydroxy derivatives of benzo[b]furan and coumarin

  摘要：

  A series of new Cu(II) complexes with the hydroxy derivatives of benzo[b]furan and coumarin have been electrochemically synthesized. The geometry of the metal-ligand interaction has been described using the single crystal X-ray diffraction method and X-ray absorption spectroscopy. Two ligands are bonded to the metal cation via the acetyl and deprotonated hydroxyl O atoms. The centrosymmetric coordination polyhedron of Cu(II) exhibits a square-planar geometry (CuO4), with both ligands coordinating in the chelating mode. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.05.042