| 101461-87-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• CAS: 101461-87-4
• 化学式: C₉H₃₂P₃W*K
• 分子量: 456.223
• InChiKey: DJUZTUJQAAVKTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.26
• 重原子数：
  14.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  、 [Zr(η-C5Me5)Cl3] * 2 tetrahydrofuran 以 四氢呋喃 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  The lanthanide-hydrogen-transition metal compounds: [{(PMe3)3WH5}2Yb·L3] and [{(η-C5H5)2NbH2}2Yb·L3] where L3 = (MeOCH2CH2)2O, and related studies

  摘要：

  The preparation of lanthanide-hydrogen-transition metal compounds [{W(PMe(3))(3)H-5}Yb-2 . diglyme] and [{Nb(eta-C5H5)(2)H-2}Yb-2 . diglyme] from the potassium salts [W(PMe(3))(3)H-5][K] and ''[Nb(eta-C5H5)(2)H-2][K]'' and YbI2 are described. Their X-ray crystal structures and NMR data indicate the presence of W(mu-H-3)Yb or W(mu-H)(2)Nb groups, respectively. The related Group IV metallocene compounds [Hf(eta-C5H5)(2)CIW(PMe(3))(3)H-5], [Hf(eta-C(5)H(4)Me)(2)ClW(PMe(3))(3)H-5], [Zr(eta-C(5)H(4)Me)(2)ClW(PMe(3))(3)H-5] and [Zr(eta-C(5)Me(5)) Cl2W(PMe(3))(3)H-5] have been prepared and the crystal structure of [Zr(eta-C(5)Me(5))Cl2W(PMe(3))(3)H-5] has been determined.

  DOI：

  10.1016/0277-5387(95)00183-s
• 作为产物：
  描述：

  WH6(PMe3)3 、 potassium hydride 以 四氢呋喃 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Transition metal–hydrogen–alkali metal bonds: syntheses and structures of W(PMe₃)₃H₅Na(15-crown-5), W(PMe₃)₃H₅K(18-crown-6), and [W(PMe₃)₃H₅Li]₄

  摘要：

  用 BunLi、NaH 或 KH 处理 W(PMe3)3H6，可得到 W(PMe3)3H5M，M = Li、Na 或适当的冠醚 W(PMe3)3H5Na(15-crown-5) 和 W(PMe3)3H5(18-crown-6)：钠和钾的冠醚化合物以及 [W(PMe3)3H5Li]4 的晶体结构已经确定。

  DOI：

  10.1039/c39850001462

文献信息

• New lanthanide–hydrogen–transition metal compounds: [{(PMe₃)₃WH₅}₂Yb·L₃] and [{(η-C₅H₅)₂NbH₂}₂Yb·L₃] where L₃=(MeOCH₂CH₂)₂O
  作者：Malcolm L. H. Green、Andrew K. Hughes、Despo M. Michaelidou、Philip Mountford

  DOI：10.1039/c39930000591

  日期：——

  The new lanthanide–hydrogen–transition metal compounds [[PMe3)3WH5}2Yb·L3] and [(η-C5H5)2NbH2}2Yb·L3], where L3=(MeOCH2CH2)2O, are prepared and their crystal structures determined.

  制备了新的镧系元素-氢-过渡金属化合物[[PMe3)3WH5}2Yb·L3]和[(·-C5H5)2NbH2}2Yb·L3]，其中L3=(MeOCH2CH2)2O，并确定了它们的晶体结构。
• Transition metal–hydrogen–alkali metal bonds: synthesis and crystal structures of [K(18-crown-6)][W(PMe₃)₃H₅], [Na(15-crown-5)][W(PMe₃)₃H₅] and [{W(PMe₃)₃H₅Li}₄] and related studies
  作者：Adam Berry、Malcolm L. H. Green、Judith A. Bandy、Keith Prout

  DOI：10.1039/dt9910002185

  日期：——

  The new compounds K[W(PMe3)H-3(5)], [K(18-crown-6)][W(PMe3)H-3(5)] (18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane), Na[W(PMe3)H-3(5)], [Na(15-crown-5)][W(PMe3)H-3(5)], (15-crown-5 = 1,4,7,10,13-pentaoxacyclopentadecane), [W(PMe3)H-3(5)Li}4], K[W(eta-C5H5)(PMe3)H-4], [K(18-crown-6)][W(eta-C5H5)(PMe3)H-4], [K(18-crown-6)][W(eta-C5H4Et)(PMe3)H-4], K[cis-Re(PMe3)H-4(2)], [K(18-crown-6)][cis-Re(PMe3)H-4(2)], [W(PMe3(H-3(5)(SnBu(n)3)], [W(eta-C5H5)(PMe3)H-4(SnBu(n)3)], [Re(PMe3)H-4(2)(SnBu(n)3)], [H(eta-C5H5)2ZrW(PMe3)H-3(5)], [Cl(eta-C5H5)2ZrW(PMe3)H-3(5), [(Ph3P)Au}3W(PMe3)H-3(4)]Cl.xCH2Cl2 and [K(18-crown-6)][Mo(eta-C5H5)H-2] are reported. The X-ray crystal structures of [K(18-crown-6)][W(PMe3)H-3(5)], [Na(15-crown-5)][W(PMe3)H-3(5)], [W(PMe3)3H5Li}4], [K(18-crown-6)][cis-Re(PMe3)H-4(2)], [(Ph3P)Au}3W(PMe3)H-3(4)]Cl.0.15CH2Cl2 and [K(18-crown-6)][Mo(eta-C5H5)H-2] have been determined. The crystal structures of [K(18-crown-6)][W(PMe3)H-3(5)] and [Na(15-crown-5)][W(PMe3)H-3(5)] have also been determined by neutron diffraction. Evidence for the presence of a degree of covalent bonding in the systems M-H-M', where M = W and M' = Li, Na or K and M = Re, M' = K, is discussed.