2,4,6,8-Tetrakis-(2-{bis-[3-(diallyl-methyl-silanyl)-propyl]-methyl-silanyl}-ethyl)-2,4,6,8-tetramethyl-[1,3,5,7,2,4,6,8]tetroxatetrasilocane | 200441-59-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2,4,6,8-Tetrakis-(2-{bis-[3-(diallyl-methyl-silanyl)-propyl]-methyl-silanyl}-ethyl)-2,4,6,8-tetramethyl-[1,3,5,7,2,4,6,8]tetroxatetrasilocane
• CAS: 200441-59-4
• 化学式: C₉₆H₁₉₂O₄Si₁₆
• 分子量: 1859.95
• InChiKey: BPDBKZWVDLWKFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  35.39
• 重原子数：
  116.0
• 可旋转键数：
  76.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  9-硼双环[3.3.1]壬烷 、 2,4,6,8-Tetrakis-(2-{bis-[3-(diallyl-methyl-silanyl)-propyl]-methyl-silanyl}-ethyl)-2,4,6,8-tetramethyl-[1,3,5,7,2,4,6,8]tetroxatetrasilocane 在 sodium hydroxide 、 双氧水 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  外围含羟基的树枝状碳硅烷

  摘要：

  已经制备了在外围具有羟基的树枝状碳硅烷。通过使用含有与9-BBN的双键的碳硅烷树状聚合物的硼氢化和随后氧化所制备的树状聚合物来制备含羟基的树状聚合物。在碱性介质中氧化硼氢化的树枝状大分子得到定量的产率。通过1 H-和13 C-NMR光谱监测硼氢化和氧化过程。使用MALDI质谱法，在所有情况下，均已对具有羟基的碳硅烷树状大分子的统一形式进行了表征。

  DOI：

  10.1016/s0022-328x(99)00335-6
• 作为产物：
  描述：

  、 烯丙基溴化镁 以 四氢呋喃 、 乙醚 为溶剂， 生成 2,4,6,8-Tetrakis-(2-{bis-[3-(diallyl-methyl-silanyl)-propyl]-methyl-silanyl}-ethyl)-2,4,6,8-tetramethyl-[1,3,5,7,2,4,6,8]tetroxatetrasilocane
  参考文献：
  名称：

  Preparation of dendritic carbosilanes containing ethynyl groups and dicobalt hexacarbonyl clusters on the periphery

  摘要：

  Dendritic carbosilanes have been prepared by the use of 2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-2,4,6,8-tetrasila-1,3,5,7-tetraoxacyclooctane (CH2=CHMeSiO), and 1,2-bis(triallylsilyl)ethane ((CH2=CHCH2)(3)SiCH2)(2) as core molecules, diallylmethylsilyl groups ((CH2=CHCH2)(2)MeSi-) as building blocks and bisphenylethynylmethylsilyl groups ((PhC=C)(2)MeSi-) as terminating groups. The phenylethynyl-group-containing terminal generation is produced by the reaction of the chlorosilylated generation with lithium phenylacethylide. The reaction of dicobalt octacarbonyl Co,(CO), with phenylethynyl groups gave the corresponding phenylethynyl hexacarbonyl complexes (2Co(2)(CO)(6).(PhC=C)(2)MeSi-dendimer) on the periphery. The yields of the prepared dendrimers with phenylethynyl terminal groups and their cobalt carbonyl complexes are obtained nearly quantitatively. They are characterized by the use of spectroscopic analyses (H-1-, and C-13-NMR, UV and IR) as well as MALDI mass spectroscopy and elemental analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00336-8

文献信息

• Preparation and termination of carbosilane dendrimers based on a siloxane tetramer as a core molecule: silane arborols, part VIII
  作者：Chungkyun Kim、Kyungmi An

  DOI：10.1016/s0022-328x(97)00145-9

  日期：1997.11

  Starting with 2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-2,4,6,8-tetrasila-1,3,5,7-tetraoxacyclooctane (Me(CH2=CH)SiO)(4) as a core molecule, a succession of alternate platinum-catalyzed hydrosilations of all vinyl groups with HSiMeCl2,, as well as alkenylation with allylmagnesium bromide, provided the third generation (G3) as divergent growth of siloxane-based dendrimers. The reaction path of the repetitive allylation/hydrosilation cycles is controlled with NMR spectroscopic analyses. Each of the two steps provided quantitative yields of pure dendrimers. We also changed the simple construction of the G3P molecule into materials with special functions, such as by adding phenylethynyl and p-bromophenoxy groups on its periphery. (C) 1997 Elsevier Science S.A.