tris(dibromomethylsilyl)methylsilane | 186499-60-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: tris(dibromomethylsilyl)methylsilane
• 英文别名: Tris[dibromo(methyl)silyl]-methylsilane；tris[dibromo(methyl)silyl]-methylsilane
• CAS: 186499-60-5
• 化学式: C₄H₁₂Br₆Si₄
• 分子量: 651.905
• InChiKey: AYAYLWBRQQLMBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.89
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tris(dibromomethylsilyl)methylsilane 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 16.0h， 以92%的产率得到tris(methylsilyl)methylsilane
  参考文献：
  名称：

  Syntheses of Functionalized Oligosilanes

  摘要：

  A number of differently substituted isotetra- and isoheptasilanes were synthesized.

  DOI：

  10.1007/s00706-006-0463-7
• 作为产物：
  描述：

  tris(methyldiphenylsilyl)methylsilane 在 aluminum tri-bromide 、 氢溴酸 作用下， 以 苯 为溶剂， 反应 1.0h， 以93%的产率得到tris(dibromomethylsilyl)methylsilane
  参考文献：
  名称：

  Decasilahexahydrotriquinacene and Decasilaisotwistane: σ Conjugation on a Bowl Surface

  摘要：

  The first bowl-shaped oligosilane, hexadecamethyldecasilahexahydrotriquinacene (1), and a related oligosilane, hexadecamethyldecasilaisotwistane (2), were synthesized, and their structures and properties were studied. The results revealed importance of sigma conjugation on a. bowl surface:. the HOMOs of 1 are sigma orbitals delocalized on the bowl surface, whereas the LUMO is a pseudo pi* orbital on the convex and concave sides of the bowl surface.

  DOI：

  10.1021/jacs.7b00250

文献信息

• Base catalysed hydrogenation of methylbromooligosilanes with trialkylstannanes, identification of the first methylbromohydrogenoligosilanes
  作者：U. Herzog、G. Roewer

  DOI：10.1016/s0022-328x(96)06552-7

  日期：1997.1

  The Lewis base catalysed hydrogenation of methylchlorooligsilanes with trialkylstannanes can also be applied to the hydrogenation of methylbromooligosilanes. In this way methylbromohydrogenoligosilanes were prepared for the first time. Methylbromotrisilanes with an > SiBrMe middle group (e.g. SiBrMe(2)-SiBrMe-SiBrMe(2)) are hydrogenated first at this silicon atom under formation of an > SiHMe group (e.g. SiBrMe(2)-SiHMe-SiBrMe(2)). Brominated silanes containing a quarternary Si(Si)(4) unit (e.g. Si(SiBrMe(2))(4)) do not react with trialkylstannanes.
• Decasilahexahydrotriquinacene and Decasilaisotwistane: σ Conjugation on a Bowl Surface
  作者：Akihiro Tsurusaki、Yu Koyama、Soichiro Kyushin

  DOI：10.1021/jacs.7b00250

  日期：2017.3.22

  The first bowl-shaped oligosilane, hexadecamethyldecasilahexahydrotriquinacene (1), and a related oligosilane, hexadecamethyldecasilaisotwistane (2), were synthesized, and their structures and properties were studied. The results revealed importance of sigma conjugation on a. bowl surface:. the HOMOs of 1 are sigma orbitals delocalized on the bowl surface, whereas the LUMO is a pseudo pi* orbital on the convex and concave sides of the bowl surface.
• Syntheses of Functionalized Oligosilanes
  作者：Roland Fischer、Judith Baumgartner、Guido Kickelbick、Karl Hassler、Christoph Marschner

  DOI：10.1007/s00706-006-0463-7

  日期：2006.5

  A number of differently substituted isotetra- and isoheptasilanes were synthesized.