3(5)-dideuteromethylpyrazole | 52884-76-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 3(5)-dideuteromethylpyrazole
• 英文别名: 3-(Methyl-D2)pyrazol；3-dideuteriomethyl-1(2)H-pyrazole
• CAS: 52884-76-1
• 化学式: C₄H₆N₂
• 分子量: 84.0892
• InChiKey: XKVUYEYANWFIJX-DICFDUPASA-N

反应信息

• 作为反应物：
  描述：

  3(5)-dideuteromethylpyrazole 在 硫酸 、 硝酸 、 二氧化氮 作用下， 生成 3(5)-dideuteromethyl-4-nitropyrazole
  参考文献：
  名称：

  Mass spectrometry of nitroazoles: 3—ortho effects: The loss of OH˙ and H2O from methyl substituted nitrodiazoles

  摘要：

  AbstractMethyl substituted nitrodiazoles which have the substituents at adjacent positions in the ring are subject to several ortho effects. Deuterium labelling of the methyl group and the mobile N‐bonded hydrogen show that the loss of OH˙ originates from the substituents. In some cases the N‐bonded hydrogen atom participates also in the loss of OH˙ and of H2O.

  DOI：

  10.1002/oms.1210170702
• 作为产物：
  描述：

  在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 3(5)-dideuteromethylpyrazole
  参考文献：
  名称：

  Mass spectrometry of nitroazoles: 3—ortho effects: The loss of OH˙ and H2O from methyl substituted nitrodiazoles

  摘要：

  AbstractMethyl substituted nitrodiazoles which have the substituents at adjacent positions in the ring are subject to several ortho effects. Deuterium labelling of the methyl group and the mobile N‐bonded hydrogen show that the loss of OH˙ originates from the substituents. In some cases the N‐bonded hydrogen atom participates also in the loss of OH˙ and of H2O.

  DOI：

  10.1002/oms.1210170702