5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidenespiro[1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene-2,1'-siletane] | 1519018-25-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidenespiro[1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene-2,1'-siletane]
• 英文别名: 5,11-diethyl-4,6,10,12-tetramethyl-8-methylidenespiro[1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene-2,1'-siletane]
• CAS: 1519018-25-7
• 化学式: C₂₁H₃₀N₂Si
• 分子量: 338.568
• InChiKey: OCJIKDWTVQDNSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.27
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  紫外线吸收剂 UV-9 、 5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidenespiro[1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene-2,1'-siletane] 以 甲苯 为溶剂， 反应 3.0h， 生成 [2-[(4,10-Diethyl-3,5,7,9,11-pentamethyl-2,15-diaza-1-silatetracyclo[6.6.1.02,6.011,15]pentadeca-3,5,7,9-tetraen-1-yl)oxy]-4-methoxyphenyl]-phenylmethanone
  参考文献：
  名称：

  Silicon Compounds of 1,1-Bis(pyrrol-2-yl)ethenes: Molecular Structures and Chemical and Spectroscopic Properties

  摘要：

  The first examples of silicon compounds of 1,1-bis(pyrrol-2-yl)ethenes have been synthesized via salt metathesis from a 2-fold lithiated dipyrromethene and different diorganodichlorosilanes (i.e., dimethyldichlorosilane, diphenyldichlorosilane, and 1,1-dichlorosilacyclobutane). Herein we report on their molecular structures, their optical properties, and some reactivity patterns.

  DOI：

  10.1021/om400868w
• 作为产物：
  描述：

  1,1'-di-κ-(3-ethyl-2,4-dimethyl)pyrrolylethene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 9.0h， 生成 5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidenespiro[1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene-2,1'-siletane]
  参考文献：
  名称：

  Silicon Compounds of 1,1-Bis(pyrrol-2-yl)ethenes: Molecular Structures and Chemical and Spectroscopic Properties

  摘要：

  The first examples of silicon compounds of 1,1-bis(pyrrol-2-yl)ethenes have been synthesized via salt metathesis from a 2-fold lithiated dipyrromethene and different diorganodichlorosilanes (i.e., dimethyldichlorosilane, diphenyldichlorosilane, and 1,1-dichlorosilacyclobutane). Herein we report on their molecular structures, their optical properties, and some reactivity patterns.

  DOI：

  10.1021/om400868w

文献信息

• Silicon Compounds of 1,1-Bis(pyrrol-2-yl)ethenes: Molecular Structures and Chemical and Spectroscopic Properties
  作者：Alexander Kämpfe、Edwin Kroke、Jörg Wagler

  DOI：10.1021/om400868w

  日期：2014.1.13

  The first examples of silicon compounds of 1,1-bis(pyrrol-2-yl)ethenes have been synthesized via salt metathesis from a 2-fold lithiated dipyrromethene and different diorganodichlorosilanes (i.e., dimethyldichlorosilane, diphenyldichlorosilane, and 1,1-dichlorosilacyclobutane). Herein we report on their molecular structures, their optical properties, and some reactivity patterns.