1,2-bis<4-(pentamethyldisilanyl)phenyl>tetramethyldisilane | 151772-74-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-bis<4-(pentamethyldisilanyl)phenyl>tetramethyldisilane
• 英文别名: 1,2-bis[4-(pentamethyldisilanyl)phenyl]tetramethyldisilane
• CAS: 151772-74-6
• 化学式: C₂₆H₅₀Si₆
• 分子量: 531.196
• InChiKey: HQWBJOKMYSZDQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.96
• 重原子数：
  32.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,2-bis<4-(pentamethyldisilanyl)phenyl>tetramethyldisilane 、 异丁烯 以 苯 为溶剂， 反应 0.67h， 生成 4-dimethylsilyl-1-(pentamethyldisilanyl)benzene 、 4-dimethylphenylsilyl-1-(pentamethyldisilanyl)benzene 、 1-isobutyldimethylsilyl-4-pentamethyldisilanyl-2-silyl>benzene
  参考文献：
  名称：

  Silicon-carbon unsaturated compounds

  摘要：

  The p-(disilanylene)phenylene oligomers, Me3Si(Me2Si-C6H4-SiMe2)nSiMe3 with n = 2-4 (2, 3, and 4) were prepared and their photochemical behavior was investigated in a benzene solution. Photolysis of 2 in the presence of isobutene afforded 1-isobutyldi-methylsilyl-4-pentamethyldisilanyl-2-(dimethyl[4-(pentamethyldisilanyl)phenyl)silyl)benzene and its isomer in 58% and 5% yields, in addition to 4-dimethylsilyl-1-(pentamethyldisilanyl)benzene (6a) (1% yield) and 4-dimethylphenylsilyl-1-(pentamethyldisilanyl)benzene (7a) (2% yield). Irradiation of 2 in the absence of isobutene gave 6a and 7a in 2% and 5% yields. Irradiation of 3 in the presence of isobutene afforded 1-isobutyldimethylsilyl-2-dimethyl[4-(pentamethyldisilanyl)phenyl]silyl-4-{2-[4-(pentamethyldi-silanyl)phenyl]tetramethyidisilanyl}benzene (8) and 4-dimethyl[2-isobutyldimethylsilyl-5-(pentamethyldisilanyl)phenyl]silyl-1-{2-[4-(pentamethyldisilanyl)phenyl]tetramethyldisilanyl}benzene (9) in 4% and 2% yields, along with small amounts of 6a and 7a. Similar irradiation of 3 in the absence of isobutene produced 6a, 7a, and 4-pentamethyldisilanyl-1-{2-[4-(dimethylphenylsilyl)phenyl]tetra-methyldisilanyl}benzene (10) in 1%, 1%, and 2% yields. The photolysis of 4 under the same conditions gave 6a, 7a, 10, and 2-[4-(dimethylsilyl)phenyl]-1-[4-(pentamethyldisilanyl)phenyl]tetramethyldisilane (11) in 1%, 11%, 11%, and 1% yields.

  DOI：

  10.1016/0022-328x(93)80381-k
• 作为产物：
  描述：

  1,4-二溴苯 在 正丁基锂 、 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 31.0h， 生成 1,2-bis<4-(pentamethyldisilanyl)phenyl>tetramethyldisilane
  参考文献：
  名称：

  Silicon-carbon unsaturated compounds

  摘要：

  The p-(disilanylene)phenylene oligomers, Me3Si(Me2Si-C6H4-SiMe2)nSiMe3 with n = 2-4 (2, 3, and 4) were prepared and their photochemical behavior was investigated in a benzene solution. Photolysis of 2 in the presence of isobutene afforded 1-isobutyldi-methylsilyl-4-pentamethyldisilanyl-2-(dimethyl[4-(pentamethyldisilanyl)phenyl)silyl)benzene and its isomer in 58% and 5% yields, in addition to 4-dimethylsilyl-1-(pentamethyldisilanyl)benzene (6a) (1% yield) and 4-dimethylphenylsilyl-1-(pentamethyldisilanyl)benzene (7a) (2% yield). Irradiation of 2 in the absence of isobutene gave 6a and 7a in 2% and 5% yields. Irradiation of 3 in the presence of isobutene afforded 1-isobutyldimethylsilyl-2-dimethyl[4-(pentamethyldisilanyl)phenyl]silyl-4-{2-[4-(pentamethyldi-silanyl)phenyl]tetramethyidisilanyl}benzene (8) and 4-dimethyl[2-isobutyldimethylsilyl-5-(pentamethyldisilanyl)phenyl]silyl-1-{2-[4-(pentamethyldisilanyl)phenyl]tetramethyldisilanyl}benzene (9) in 4% and 2% yields, along with small amounts of 6a and 7a. Similar irradiation of 3 in the absence of isobutene produced 6a, 7a, and 4-pentamethyldisilanyl-1-{2-[4-(dimethylphenylsilyl)phenyl]tetra-methyldisilanyl}benzene (10) in 1%, 1%, and 2% yields. The photolysis of 4 under the same conditions gave 6a, 7a, 10, and 2-[4-(dimethylsilyl)phenyl]-1-[4-(pentamethyldisilanyl)phenyl]tetramethyldisilane (11) in 1%, 11%, 11%, and 1% yields.

  DOI：

  10.1016/0022-328x(93)80381-k