4-methacryloyloxy-1-((2'-methacryloyloxy-1'-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine | 1290059-22-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 4-methacryloyloxy-1-((2'-methacryloyloxy-1'-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine
• 英文别名: [2-Phenyl-2-[2,2,6,6-tetramethyl-4-(2-methylprop-2-enoyloxy)piperidin-1-yl]oxyethyl] 2-methylprop-2-enoate；[2-phenyl-2-[2,2,6,6-tetramethyl-4-(2-methylprop-2-enoyloxy)piperidin-1-yl]oxyethyl] 2-methylprop-2-enoate
• CAS: 1290059-22-1
• 化学式: C₂₅H₃₅NO₅
• 分子量: 429.557
• InChiKey: QTMCHHOBNQDYII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  65.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-hydroxy-1-((2'-hydroxy-1'-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以88%的产率得到4-methacryloyloxy-1-((2'-methacryloyloxy-1'-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine
  参考文献：
  名称：

  Self-Healing of Polymers via Synchronous Covalent Bond Fission/Radical Recombination

  摘要：

  The present paper is devoted to preparation of intrinsic self-healing polymeric materials used for structural applications. The authors introduced a novel healing chemistry based on dynamically reversible C-ON bonds, which imitates natural healing in living bodies without affecting their operations. To verify its feasibility, alkoxyamine moieties served as intermolecular links in polystyrene. Upon heating, covalent bond fission and radical recombination synchronously took place among alkoxyamine moieties. Cracked puts were thus reconnected repeatedly, without losing integrity and load bearing ability of the material even above T-g.

  DOI：

  10.1021/cm202635w

文献信息

• Self-Healing of Polymers via Synchronous Covalent Bond Fission/Radical Recombination
  作者：Chan′e Yuan、Min Zhi Rong、Ming Qiu Zhang、Ze Ping Zhang、Yan Chao Yuan

  DOI：10.1021/cm202635w

  日期：2011.11.22

  The present paper is devoted to preparation of intrinsic self-healing polymeric materials used for structural applications. The authors introduced a novel healing chemistry based on dynamically reversible C-ON bonds, which imitates natural healing in living bodies without affecting their operations. To verify its feasibility, alkoxyamine moieties served as intermolecular links in polystyrene. Upon heating, covalent bond fission and radical recombination synchronously took place among alkoxyamine moieties. Cracked puts were thus reconnected repeatedly, without losing integrity and load bearing ability of the material even above T-g.