Mn(N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester)2(1,10-phenanthroline) | 1234506-01-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Mn(N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester)2(1,10-phenanthroline)
• CAS: 1234506-01-4
• 化学式: C₃₀H₂₈MnN₈O₂S₄
• 分子量: 715.807
• InChiKey: LXIZFQXVSQDJKU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester 、 manganese (II) acetate tetrahydrate 以 甲醇 为溶剂， 以58%的产率得到Mn(N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester)2(1,10-phenanthroline)
  参考文献：
  名称：

  Synthesis, spectral and structural studies of a Mn(II) complex of [N′-(pyridine-4-carbonyl)-hydrazine]-carbodithioic acid ethyl ester and Mn(II) and Ni(II) complexes of [N′-(pyridine-4-carbonyl)-hydrazine]-carbodithioic acid methyl ester

  摘要：

  The new complexes [Mn(Hpchce)(2)(o-phen)], {2[Mn(pchcm)(o-phen)(2)])center dot 7H(2)O and [Ni(Hpchcm)(o-phen)(2)]Cl center dot CH3OH with [N'-(pyridine-4-carbonyl)-hydrazine]-carbodithioic acid ethyl ester (H(2)pchce) and [N'-(pyridine-4-carbonyl)-hydrazinej-carbodithioic acid methyl ester (H(2)pchcm) have been synthesized, containing o-phenanthroline (o-phen) as a coligand. These ligands and their complexes have been characterized by elemental analyses, IR, magnetic susceptibility and single crystal X-ray data. H2pchce (2), [Mn(Hpchce)(2)(o-phen)] (3) (2[Mn(pchcm)(o-phen)(2)])center dot 7H(2)O (4) and [Ni(Hpchcm)(o-phen)(2)]Cl center dot CH3OH (5) crystallized in the monoclinic system, space group Pc, C2/c, P21/n and P21/n, respectively. The (N, O) donor sites of the bidentate ligands chelate the Mn(II) and Ni(II) centers forming a five-membered CN2OM ring. The resulting complexes are paramagnetic and have a distorted octahedral geometry. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.02.038