2-N-(2,2,6,6-tetramethyl-1-oxidopiperidin-4-yl)-3-N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxamide | 307307-46-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 2-N-(2,2,6,6-tetramethyl-1-oxidopiperidin-4-yl)-3-N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxamide
• CAS: 307307-46-6
• 化学式: C₂₇H₄₂N₄O₄
• 分子量: 486.655
• InChiKey: GFULLJRHKNCJRZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  105
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-N-(2,2,6,6-tetramethyl-1-oxidopiperidin-4-yl)-3-N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxamide 以 苯 为溶剂， 生成 5-N-(2,2,6,6-tetramethyl-1-oxidopiperidin-4-yl)-1-N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)tetracyclo[3.2.0.02,7.04,6]heptane-1,5-dicarboxamide
  参考文献：
  名称：

  Preparation and Properties of Photo-Functional Systems with Nitroxide Radicals

  摘要：

  Series of TEMPO-substituted norbornadiene, spiropyran and anthracene derivatives have been prepared; their light-induced structural change to the corresponding qudricyclanes. merocyanines or anthracene-dimers and the reverse reactions to the starting materials have been studied. The antiferromagnetic or ferromagnetic behavior observed in norbornadienes/anthracenes was found to be preserved in the corresponding quadricyclanes/anthracene-dimers in spite of the difference of their Weiss temperatures, whereas switching of the intermolecular magnetic interactions was observed in spiropyran/merocyanine systems.

  DOI：

  10.1080/10587250108023683
• 作为产物：
  描述：

  5-N-(2,2,6,6-tetramethyl-1-oxidopiperidin-4-yl)-1-N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)tetracyclo[3.2.0.02,7.04,6]heptane-1,5-dicarboxamide 在 palladium on activated charcoal 作用下， 以 乙酸乙酯 为溶剂， 以95%的产率得到2-N-(2,2,6,6-tetramethyl-1-oxidopiperidin-4-yl)-3-N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxamide
  参考文献：
  名称：

  Nakatsuji, Shin'ichi; Ogawa, Yuya; Takeuchi, Soichi, Journal of the Chemical Society. Perkin Transactions 2 (2001), 2000, # 9, p. 1969 - 1975

  摘要：

  DOI：

文献信息

• Preparation and Properties of Photo-Functional Systems with Nitroxide Radicals
  作者：Shin'ichi Nakatsuji、Soichi Takeuchi、Takeo Ojima、Yuya Ogawa、Hiroki Akutsu、Jun-Ichi Yamada

  DOI：10.1080/10587250108023683

  日期：2001.2.1

  Series of TEMPO-substituted norbornadiene, spiropyran and anthracene derivatives have been prepared; their light-induced structural change to the corresponding qudricyclanes. merocyanines or anthracene-dimers and the reverse reactions to the starting materials have been studied. The antiferromagnetic or ferromagnetic behavior observed in norbornadienes/anthracenes was found to be preserved in the corresponding quadricyclanes/anthracene-dimers in spite of the difference of their Weiss temperatures, whereas switching of the intermolecular magnetic interactions was observed in spiropyran/merocyanine systems.
• Nakatsuji, Shin'ichi; Ogawa, Yuya; Takeuchi, Soichi, Journal of the Chemical Society. Perkin Transactions 2 (2001), 2000, # 9, p. 1969 - 1975
  作者：Nakatsuji, Shin'ichi、Ogawa, Yuya、Takeuchi, Soichi、Akutsu, Hiroki、Yamada, Jun-Ichi、Naito, Akira、Sudo, Kyoko、Yasuoka, Noritake

  DOI：——

  日期：——