| 285139-29-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 285139-29-9
• 化学式: C₂₄H₆₂HgP₄Pt₂
• 分子量: 1065.4
• InChiKey: OVXPBJFVCUCGTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.57
• 重原子数：
  31.0
• 可旋转键数：
  18.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 苯甲腈 、 汞 在 sodium perchlorate 作用下， 以 苯甲腈 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical synthesis and spectroscopic characterization of a mercury–platinum–hydride complex

  摘要：

  Controlled potential bulk reductive electrolysis of trans-[PtI2(PEt3)(2)] in 5:2 C6H5CN:C6H6 (saturated with NaClO4)at a Hg pool electrode at -1.5 V (vs. Ag/AgCl) and at approximately 0 degrees C, yielded two compounds detectable by P-31{H-1} NMR spectroscopy. One compound was the starting material, trans-[PtI2(PEt3)(2)], while the other displayed a complex spectrum. Analysis of the H-1, P-31{H-1} and Pt-195{H-1} NMR spectra suggested that the compound contained an unaccounted for spin one-half nucleus. Scanning electron microscopy-energy dispersive spectroscopy and inductively coupled plasma atomic emission spectroscopy indicated that the compound contained mercury and the spectra could be satisfactorily interpreted in terms of a mercury-platinum-hydride structure. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00023-2