Zn(en)2Cl2 | 163808-99-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Zn(en)2Cl2
• 英文别名: dichlorozinc;ethane-1,2-diamine
• CAS: 163808-99-9；93251-79-7
• 化学式: C₄H₁₆Cl₂N₄Zn
• 分子量: 256.494
• InChiKey: VYPUEWMOSRGKOS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  盐酸 、 sodium hydroxide 、 水 、 (氨基亚甲基)二膦酸 、 Zn(en)2Cl2 以 水 为溶剂， 以75%的产率得到Na4Zn(aminomethylenediphosphonate(+1H))2*4H2O
  参考文献：
  名称：

  Metal phosphonates based on aminomethylenediphosphonate: Syntheses and characterization of Na4Zn{NH3CH(PO3)2}2·4H2O, Ni{NH3CH(PO3H)2}2·xH2O and NaNi2{NH3CH(PO3)(PO3H0.5)}2(H2O)2·2H2O

  摘要：

  This paper describes the syntheses of three transition metal diphosphonate compounds: Na4Zn{NH3CH(PO3)(2)}(2) center dot 4H(2)O (1), Ni{NH3CH(PO3H)(2)}(2)center dot xH(2)O (2) and NaNi2{NH3CH(PO3)(PO3H0 (5))}(2)(H2O)(2)center dot 2H(2)O (3). Compound 1 contains chains of [Zn(NH3CH(PO3)(2)}(2)](n)(4n-) made up of corner-sharing ZnO6 octahedra and CPO3 tetrahedra, which are further connected by tetramers of edge-sharing NaO6 octahedra, forming a three-dimensional open-framework structure. Compound 2 shows a square-grid layer structure where the NiO6 octahedra are corner shared with CPO3 tetrahedra. The adjacent layers are linked by strong interlayer hydrogen bonds, resulting in a three-dimensional open-network structure with channels where the lattice water molecules reside. The structure of compound 3 is analogous to that of NaCo2{NH3CH(PO3)(PO3H0.5)}(2)(H2O)(2)center dot xH(2)O in which layers of Ni-2{NH3CH(PO3)(PO3H0.5)}(2)(H2O)(2) are connected by NaO6 linkages into an open-framework structure. The magnetic studies show that weak antiferromagnetic interactions are mediated between the nickel ions in compounds 2 and 3. Crystal data for 1: triclinic, space group P-1, a = 5.551(2) angstrom, b = 6.166(2) angstrom, c = 12.424(4) angstrom, alpha = 92.422(6)degrees, beta = 92.687(7)degrees, gamma = 93.926(6)degrees, V = 423.3(2) angstrom(3), Z = 2. For 2: triclinic, space group P-1, a = 9.043(1) angstrom, b = 9.180(1) angstrom, c = 9.271(1) angstrom, alpha = 89.693(3)degrees, beta = 70.202(3)degrees, gamma = 89.530(3)degrees, V = 724.1(2) angstrom(3), Z = 2. (C) 2005 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2005.10.041
• 作为产物：
  描述：

  氧化锌 、 氯化铵 、 乙二胺 、 乙腈 以92%的产率得到
  参考文献：
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  摘要：

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文献信息

• ——
  作者：KOKOZEJ V. N.、 PAVLENKO V. A.、 NEVESENKO N. D.

  DOI：——

  日期：——