1,2,3,4-tetrafluoropentacene | 1297348-21-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 并五苯
• 英文名称: 1,2,3,4-tetrafluoropentacene
• CAS: 1297348-21-0
• 化学式: C₂₂H₁₀F₄
• 分子量: 350.315
• InChiKey: CNHYYDGPMZVKSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,2,3,4-tetrafluoropentacene 以 氘代四氢呋喃 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  The synthesis and ambipolar charge transport properties of 1,2,3,4-tetrafluoropentacene

  摘要：

  1,2,3,4-Tetrafluoropentacene is prepared from a soluble precursor containing a carbonyl bridge across the central benzene ring. It underwent dimerization readily in solution, yet displayed a high stability in the solid state. While fabricated into OFET devices, it exhibited an ambipolar charge transport characteristic. Its spectral and electronic properties are described. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.126
• 作为产物：
  描述：

  (5R,14S)-8,9,10,11-tetrafluoro-5,14-dihydro-5,14-methanopentacen-15-one 反应 0.08h， 以100%的产率得到1,2,3,4-tetrafluoropentacene
  参考文献：
  名称：

  The synthesis and ambipolar charge transport properties of 1,2,3,4-tetrafluoropentacene

  摘要：

  1,2,3,4-Tetrafluoropentacene is prepared from a soluble precursor containing a carbonyl bridge across the central benzene ring. It underwent dimerization readily in solution, yet displayed a high stability in the solid state. While fabricated into OFET devices, it exhibited an ambipolar charge transport characteristic. Its spectral and electronic properties are described. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.126

文献信息

• FLUORINE-CONTAINING POLYCYCLIC AROMATIC COMPOUND, FLUORINE-CONTAINING POLYMER, ORGANIC THIN FILM AND ORGANIC THIN FILM DEVICE
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2133321A1

  公开（公告）日：2009-12-16

  A fluorine-containing polycyclic aromatic compound represented by the following formula (I) is provided. According to present invention, a novel compound capable of being utilized as an organic n-type semiconductor having an excellent electron transport property is provided, wherein in formula (I), Ar1 and Ar2 each independently represent an aromatic hydrocarbon group having at least six carbon atoms or a heterocyclic group having at least four carbon atoms; R1, R2, R3 and R4 each independently represent a hydrogen atom, a halogen atom, or a monovalent group; R5 and R6 each independently represent a hydrogen atom or a monovalent organic group that may be substituted with a substituent; s1 and t1 each independently represent an integer of at least 2; with the proviso that at least one of R5 and R6 is the abovementioned monovalent organic group where at least one of all the hydrogen atoms of the monovalent organic group including the substituent is substituted with a fluorine atom.

  本发明提供了一种由下式(I)表示的含氟多环芳烃化合物。根据本发明，提供了一种可用作有机 n 型半导体的新型化合物，该化合物具有优异的电子传输特性、 式（I）中，Ar1 和 Ar2 各自独立地代表具有至少六个碳原子的芳香烃基团或具有至少四个碳原子的杂环基团；R1、R2、R3 和 R4 各自独立地代表氢原子、卤素原子或一价基团；R5 和 R6 各自独立地代表氢原子或可被取代基取代的一价有机基团；s1和t1各自独立地代表至少2的整数；但R5和R6中至少有一个是上述一价有机基团，其中包括取代基在内的一价有机基团的所有氢原子中至少有一个被氟原子取代。