[Y(CH₂SiMe₃)₂(Me₃TACD)] | 1030955-94-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [Y(CH₂SiMe₃)₂(Me₃TACD)]
• 英文别名: [Y(CH₂SiMe₃)₂(Me₃(1,4,7,10-tetraazacyclododecane))]
• CAS: 1030955-94-2
• 化学式: C₁₉H₄₇N₄Si₂Y
• 分子量: 476.686
• InChiKey: ZCWGFBQOCHZGTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Y(CH₂SiMe₃)₂(Me₃TACD)] 、 氢气 以 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  由 Cyclen 衍生的 [NNNN] 大环辅助配体稳定的稀土金属烷基和氢化物配合物

  摘要：

  由单阴离子[NNNN]大环负载的二烷基配合物合成了三核稀土金属氢化物配合物，并显示出有效催化烯烃的氢化硅烷化。

  DOI：

  10.1021/ja801771u
• 作为产物：
  描述：

  bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III) 、 1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane 以 正戊烷 为溶剂， 生成 [Y(CH₂SiMe₃)₂(Me₃TACD)]
  参考文献：
  名称：

  由 Cyclen 衍生的 [NNNN] 大环辅助配体稳定的稀土金属烷基和氢化物配合物

  摘要：

  由单阴离子[NNNN]大环负载的二烷基配合物合成了三核稀土金属氢化物配合物，并显示出有效催化烯烃的氢化硅烷化。

  DOI：

  10.1021/ja801771u

文献信息

• Yttrium Dihydride Cation [YH₂(THF)₂]⁺_<i>n</i>: Aggregate Formation and Reaction with (NNNN)-Type Macrocycles
  作者：Stefan Arndt、Mathias U. Kramer、Waldemar Fegler、Yumiko Nakajima、Iker Del Rosal、Romuald Poteau、Thomas P. Spaniol、Laurent Maron、Jun Okuda

  DOI：10.1021/acs.organomet.5b00422

  日期：2015.8.10

  Monocationic bis(hydrocarbyl)yttrium complexes [YR2(THF)(2)] [A] (R = CH2SiMe3, CH2C6H4-o-NMe2; A = weakly coordinating anion) underwent hydrogenolysis using dihydrogen or phenylsilane to give a mixture of polynuclear solvent-stabilized dihydride cations [YHz(THF)(2)](n)[A](n). The mixture composition as well as the nudearity n depended on the starting material, solvent, and reaction conditions. NMR spectroscopic data in solution and X-ray diffraction data suggested that the main product was tetranuclear, although conclusive structural data were not obtained. DFT calculations supported a closo-type tetrahedral [YH2(THF)(2)](4)(4+) core. The hydridic character of these cations was revealed by their reaction with benzophenone to give the bis(diphenylmethoxy) cation [Y(OCHPh2)(2)(THF)(4)][AlR4]. The reaction of this cluster with the (NNNN)-type macrocycle Me(4)TACD under dihydrogen gave the dinuclear tetrahydride dication with quadruply bridging hydride ligands, [Y-2(mu-H)(4)(Me(4)TACD)(2)][A](2), analogous to the previously characterized lutetium derivative. NH-acidic (Me(3)TACD)H gave the dinudear dihydride dication [Y-2(mu-H)(2)(Me(3)TACD)(2)(THF)(2)] [A](2).