tetrakisdecylammonium methylcarbonate | 1338579-12-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: tetrakisdecylammonium methylcarbonate
• 英文别名: Methyl carbonate;tetrakis-decylazanium
• CAS: 1338579-12-6
• 化学式: C₂H₃O₃*C₄₀H₈₄N
• 分子量: 654.158
• InChiKey: RWISEFJIONSIRX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  13.34
• 重原子数：
  46
• 可旋转键数：
  36
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.98
• 拓扑面积：
  49.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  四癸基氢氧化铵 、 碳酸二甲酯 以 甲醇 为溶剂， 生成 tetrakisdecylammonium methylcarbonate
  参考文献：
  名称：

  CROSSLINKABLE COMPOSITION CROSSLINKABLE WITH A LATENT BASE CATALYST

  摘要：

  本发明涉及一种交联组合物，其包括至少一种可交联组分，可由一种潜在碱交联催化剂交联，该交联催化剂包括根据式1的取代碳酸盐，其中X+代表阳离子，R为氢、烷基、芳基或芳基烷基，且所述交联组合物包括0.1-10重量％，优选0.1-5，更优选0.2-3，最优选0.5-1.5重量％的水（相对于交联组合物的总重量）。本发明还涉及一种包括根据本发明的交联组合物的涂料组合物，一种新型催化剂组合物以及所述催化剂组合物的使用作为潜在碱交联催化剂在涂料组合物中的用途，优选在RMA可交联组合物中。

  公开号：

  US20130041091A1

文献信息

• Crosslinkable composition crosslinkable with a latent base catalyst.
  申请人：Nuplex Resins B.V.

  公开号：EP2374836A1

  公开（公告）日：2011-10-12

  The present invention relates to a crosslinkable composition comprising at least one crosslinkable component and a latent base crosslinking catalyst, which crosslinkable composition has a solids content of at least 55 wt% (dry weight after crosslinking relative to the total weight of the crosslinking composition) wherein the latent base catalyst is a substituted carbonate salt according to formula 1 wherein X+ represents a cation, preferably a quaternary ammonium or phosphonium, and wherein R is hydrogen, alkyl, aryl or aralkyl group. The invention relates in particular to a composition crosslinkable by Real Michael Addition (RMA) reaction wherein a component with at least 2 activated unsaturated groups and a component with at least 2 acidic protons C-H in activated methylene or methine groups react and crosslink to each other in the presence of a strong base catalyst. The invention further relates to a coating composition comprising the crosslinkable composition according to the invention, a novel catalyst composition and to the use of said catalyst composition according to the invention as a latent base crosslinking catalyst in coating compositions, preferably in RMA crosslinkable compositions.

  本发明涉及一种可交联组合物，该组合物包括至少一种可交联组分和一种潜碱交联催化剂，该可交联组合物的固体含量至少为 55 wt%（交联后的干重相对于交联组合物的总重量），其中潜碱催化剂是一种根据式 1 所示的取代碳酸盐 其中 X+ 代表阳离子，最好是季铵或鏻，R 是氢、烷基、芳基或芳烷基。本发明尤其涉及一种可通过真实迈克尔加成（RMA）反应交联的组合物，其中至少有 2 个活化不饱和基团的组分和至少有 2 个酸性质子 C-H 在活化亚甲基或甲基中的组分在强碱催化剂存在下发生反应并相互交联。本发明进一步涉及一种包含根据本发明的可交联组合物、新型催化剂组合物的涂料组合物，以及根据本发明的所述催化剂组合物作为潜碱交联催化剂在涂料组合物中的使用，最好是在 RMA 可交联组合物中的使用。
• CROSSLINKABLE COMPOSITION
  申请人：Nuplex Resins B.V.

  公开号：EP2985308A1

  公开（公告）日：2016-02-17

  The present invention relates to a crosslinkable composition comprising reactive components A and B each comprising at least 2 reactive groups wherein the at least 2 reactive groups of component A are acidic protons (C-H) in activated methylene or methine groups and the at least 2 reactive groups of component B are activated unsaturated groups (C=C) to achieve crosslinking by Real Michael Addition (RMA) in the presence of base catalyst C wherein the component A is a malonate containing component and wherein the crosslinkable composition comprises in addition to the malonate component A, a second component A2 comprising reactive acidic protons having a higher acidity than component A and also is reactive towards component B.

  本发明涉及一种可交联组合物，该组合物由各自包含至少 2 个活性基团的活性组分 A 和 B 组成，其中组分 A 的至少 2 个活性基团为活化亚甲基或甲基中的酸性质子（C-H），组分 B 的至少 2 个活性基团为活化不饱和基团（C=C），以便在碱催化剂 C 的存在下通过真正迈克尔加成（RMA）实现交联，其中组分 A 为含丙二酸的组分，而可交联组合物除丙二酸组分 A 外还包括第二种组份 A2，它含有活性酸性质子，酸度高于组份 A，并且对组份 B 具有活性。
• Crosslinkable composition crosslinkable with a latent base catalyst
  申请人：NUPLEX RESINS B.V.

  公开号：US20160168320A1

  公开（公告）日：2016-06-16

  The present invention relates to a crosslinkable composition comprising at least one crosslinkable component and a latent base crosslinking catalyst, which crosslinkable composition has a solids content of typically at least 55 wt (dry weight after crosslinking relative to the total weight of the crosslinking composition) wherein the latent base catalyst is a substituted carbonate salt according to formula 1 wherein X + represents a non acidic cation, preferably a quaternary ammonium or phosphonium, and wherein R is hydrogen, alkyl, aryl or aralkyl group. The invention relates in particular to a composition crosslinkable by Real Michael Addition (RMA) reaction wherein a component with at least 2 activated unsaturated groups and a component with at least 2 acidic protons C—H in activated methylene or methine groups, preferably malonate react and crosslink to each other in the presence of the base catalyst. The invention further relates to a coating composition comprising the crosslinkable composition according to the invention, a novel catalyst composition and to the use of said catalyst composition according to the invention as a latent base crosslinking catalyst in coating compositions, preferably in RMA crosslinkable compositions.
• US8962725B2
  申请人：——

  公开号：US8962725B2

  公开（公告）日：2015-02-24
• US9181453B2
  申请人：——

  公开号：US9181453B2

  公开（公告）日：2015-11-10