2,2-Dimethyl-propionic acid (1R,2S,5R)-2-(1-methyl-1-phenyl-ethyl)-5-[(Z)-4-(2-oxo-5-phenylsulfanyl-pyrrolidin-1-yl)-but-1-enyl]-cyclohexyl ester | 92845-25-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 2,2-Dimethyl-propionic acid (1R,2S,5R)-2-(1-methyl-1-phenyl-ethyl)-5-[(Z)-4-(2-oxo-5-phenylsulfanyl-pyrrolidin-1-yl)-but-1-enyl]-cyclohexyl ester
• CAS: 92845-25-5
• 化学式: C₃₄H₄₅NO₃S
• 分子量: 547.802
• InChiKey: WEGBJVPTDHLSPK-VBRRIOQUSA-N

反应信息

• 作为反应物：
  描述：

  2,2-Dimethyl-propionic acid (1R,2S,5R)-2-(1-methyl-1-phenyl-ethyl)-5-[(Z)-4-(2-oxo-5-phenylsulfanyl-pyrrolidin-1-yl)-but-1-enyl]-cyclohexyl ester 在 偶氮二异丁腈 、 三正丁基氢锡 作用下， 以 苯 为溶剂， 反应 1.5h， 生成 2,2-Dimethyl-propionic acid (1R,2S,5R)-2-(1-methyl-1-phenyl-ethyl)-5-[(E)-4-(2-oxo-pyrrolidin-1-yl)-but-1-enyl]-cyclohexyl ester 、 2,2-Dimethyl-propionic acid (1R,2S,5S)-2-(1-methyl-1-phenyl-ethyl)-5-((1R,7aR)-5-oxo-hexahydro-pyrrolizin-1-ylmethyl)-cyclohexyl ester 、 2,2-Dimethyl-propionic acid (1R,2S,5S)-2-(1-methyl-1-phenyl-ethyl)-5-((1S,7aR)-5-oxo-hexahydro-pyrrolizin-1-ylmethyl)-cyclohexyl ester
  参考文献：
  名称：

  .alpha.-Acylamino radical cyclizations: syntheses of isoretronecanol

  摘要：

  DOI：

  10.1021/ja00338a034