iron(II) hexafluorozirconate | 30868-53-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: iron(II) hexafluorozirconate
• CAS: 30868-53-2
• 化学式: F₆Zr*Fe
• 分子量: 261.061
• InChiKey: GEXDULJLLZUWQQ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  2.52
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  4-氨基-1,2,4-三氮唑 、 iron(II) hexafluorozirconate 在 ascorbic acid 作用下， 以 乙醇 为溶剂， 以50%的产率得到[iron(II)(4-amino-1,2,4-triazole)3](hexafluorozirconate)
  参考文献：
  名称：

  Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions

  摘要：

  New one-dimensional spin transition coordination polymers of formula [Fe(NH(2)trZ)(3)](AF(6)) center dot nH(2)O (A = Ti, Zr, Sn; NH(2)trz = 4-amino-1,2,4-triazole) have been synthesized in MeOH and EtOH media. These materials display an abrupt and hysteretic spin transition around 200 K as well as a reversible thermochromic effect on, cooling. A preliminary evaluation of the lattice dynamics in the high-spin and low-spin states is presented. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.009
• 作为产物：
  描述：

  hexafluorozirconic acid 、 铁粉 以 not given 为溶剂， 生成 iron(II) hexafluorozirconate
  参考文献：
  名称：

  Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions

  摘要：

  New one-dimensional spin transition coordination polymers of formula [Fe(NH(2)trZ)(3)](AF(6)) center dot nH(2)O (A = Ti, Zr, Sn; NH(2)trz = 4-amino-1,2,4-triazole) have been synthesized in MeOH and EtOH media. These materials display an abrupt and hysteretic spin transition around 200 K as well as a reversible thermochromic effect on, cooling. A preliminary evaluation of the lattice dynamics in the high-spin and low-spin states is presented. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.009