trimethylsilyliminobis(vinyldimethylsilane) | 24676-61-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: trimethylsilyliminobis(vinyldimethylsilane)
• 英文别名: Bis(dimethylvinylsilyl)trimethylsilylamine；bis(vinyldimethylsilyl)trimethylsilylamine；[[[Ethenyl(dimethyl)silyl]-trimethylsilylamino]-dimethylsilyl]ethene
• CAS: 24676-61-7
• 化学式: C₁₁H₂₇NSi₃
• 分子量: 257.599
• InChiKey: KVTNHXVMXZJNIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.98
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trimethylsilyliminobis(vinyldimethylsilane) 、 [4-[4-(4-octoxybenzoyl)oxyphenyl]phenyl] 2-[5-[dimethylsilyloxy(dimethyl)silyl]pentoxy]-4-octoxybenzoate 生成
  参考文献：
  名称：

  Elsaesser, R.; Mehl, G. H.; Goodby, J. W., Phosphorus, Sulfur and Silicon and the Related Elements, 2001, vol. 169, p. 17 - 20

  摘要：

  DOI：
• 作为产物：
  描述：

  三甲基氯硅烷 、 1,1,3,3-四甲基-1,3-二乙烯基二硅氮烷 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以91%的产率得到trimethylsilyliminobis(vinyldimethylsilane)
  参考文献：
  名称：

  Hydrosilylation reactions of tetramethyldisilazanes and their derivatives

  摘要：

  Hydrosilylation between 1,1,3,3-tetramethyldisilazane (A) and 1,3-divinyl-1,1,3,3-tetramethyldisilazane (B) occurs rapidly at 90 degreesC in the presence of Karstedt's catalyst to give a product mixture consisting mainly of large macrocycles. Deprotonation-substitution reactions of these macrocycles were largely unsuccessful. Trimethylsilylated and methylated derivatives of A and B were prepared and used in hydrosilylation reactions. High-yield formation of large macrocycles was observed when the trimethylsilylated or methylated derivative of B was reacted with unmodified A. The methylated product was successfully deprotonated and functionalized with trimethylsilyl groups. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01448-1

文献信息

• Seyferth, Dietmar; Friedrich, Holger; Krska, Shane W., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1994, vol. 49, # 12, p. 1818 - 1826
  作者：Seyferth, Dietmar、Friedrich, Holger、Krska, Shane W.

  DOI：——

  日期：——
• Nematic Dendrimers Based on Carbosilazane Cores
  作者：Ralf Elsäßer、Georg H. Mehl、John W. Goodby、Michael Veith

  DOI：10.1002/1521-3773(20010716)40:14<2688::aid-anie2688>3.0.co;2-s

  日期：2001.7.16

  The controlled synthesis of nematic nanophase-separated materials poses an attractive synthetic challenge. The use of carbosilazane multipodes and dendrimers (such as 1) in conjunction with laterally attached mesogens allows the systematic investigation of the structure-property relationships of room-temperature nematic liquid crystals.
• Elsaesser, R.; Goodby, J. W.; Mehl, G. H., Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 2003, vol. 402, p. 1 - 8
  作者：Elsaesser, R.、Goodby, J. W.、Mehl, G. H.、Rodriguez-Martin, D.、Richardson, R. M.、Photinos, D. J.、Veith, M.

  DOI：——

  日期：——