chlorocarbonic acid tridecyl ester | 53220-11-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: chlorocarbonic acid tridecyl ester
• 英文别名: Tridecylchlorformiat；Chlorokohlensaeure-tridecylester；Chlorameisensaeure-tridecylester；Tridecylchloroformate；tridecyl carbonochloridate
• CAS: 53220-11-4
• 化学式: C₁₄H₂₇ClO₂
• 分子量: 262.82
• InChiKey: RLDVFPKFKUYGHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  17
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  chlorocarbonic acid tridecyl ester 、 2-(1H-苯并咪唑-2-基)-1H-苯并咪唑 以to give 1,1'-bis(tridecyloxycarbonyl)-2,2'-bibenzimidazole in 86% purity的产率得到1,1'-bis(tridecyloxycarbonyl)-2,2'-bibenzimidazole
  参考文献：
  名称：

  Process for the extraction of metal values and novel metal extractants

  摘要：

  使用1,1'-取代的2,2'-双咪唑或双苯并咪唑化合物，从含卤化物或假卤化物阴离子的水溶液中提取金属价值。对于从氯化物浸出液中萃取锌和铜的溶剂萃取非常有用。

  公开号：

  US04822880A1

文献信息

• Process for the extraction of metal values with bisimidazole metal
  申请人：Imperial Chemical Industries PLC

  公开号：US04696801A1

  公开（公告）日：1987-09-29

  Metal values are extracted from aqueous solutions containing halide or pseudohalide anion using 1,1'-substituted 2,2'-biimidazole or bibenzimidazole compounds. Useful for the solvent extraction of zinc and copper from chloride leach solutions.

  使用1,1'-取代的2,2'-双咪唑或双苯并咪唑化合物从含卤或伪卤阴离子的水溶液中提取金属价值。适用于从氯化物浸出溶液中溶剂萃取锌和铜。
• Bis-bibenzimidazole composition
  申请人：ZENECA LIMITED

  公开号：EP0513966A2

  公开（公告）日：1992-11-19

  A composition of bibenzimidazoles of the Formula (I) : wherein X&Y which may be the same or different and, taken together, contain a total of from 12 to 52 saturated carbon atoms, are (a) each selected from -R, -COR, -CH2COOR, -CH(COOR)2 and -COOR; or (b) together form a group selected from and wherein R is an optionally substituted hydrocarbyl group, A & B taken together with the two carbon atoms to which they are linked form an optionally substituted benzene ring ; and C & D taken together with the two carbon atoms to which they are linked form an optionally substituted benzene ring ; characterised in that at least 50% by weight of the bibenzimidazoles in the composition are of Formula (II) wherein X and Y are as hereinbefore defined ; T, U, V & W which may be the same or different, are H, R1 or OR1 provided at least one of T, U, V & W is R1 or OR1 ; and R1 is C1-6-alkyl ; which are suitable for use in the extraction of zinc from aqueous solutions of zinc in the presence of other metals.

  式 (I) 的联苯并咪唑组合物： 其中 X&Y (a) 各自选自-R、-COR、-CH2COOR、-CH(COOR)2 和-COOR；或 (b) 共同组成选自以下的基团 和 其中 R 是任选取代的烃基、 A 和 B 与相连的两个碳原子共同构成一个任选取代的苯环；以及 C 和 D 与相连的两个碳原子共同形成一个任选取代的苯环； 其特征在于，按重量计，组合物中至少 50%的联苯并咪唑为式 (II) 其中 X 和 Y 如前定义 T、U、V 和 W 可以是相同或不同的 H、R1 或 OR1，条件是 T、U、V 和 W 中至少有一个是 R1 或 OR1；以及 R1 是 C1-6 烷基； 适用于从含有其他金属的锌水溶液中萃取锌。
• Diaryl alkane derivatives containing an alicyclic group, their preparation and their therapeutic and prophylactic uses
  申请人：SANKYO COMPANY LIMITED

  公开号：EP0790235A1

  公开（公告）日：1997-08-20

  Compounds of formula (I): [in which: R1 represents a saturated heterocyclic group attached to the bond or group represented by A through a ring carbon atom; R2a, R2b, R2c, R3a, R3b, R3c and R3d are hydrogen or various other groups or atoms; and A represents a single bond or an alkylene group having from 1 to 6 carbon atoms] are serotonin 2 receptor antagonists and have the ability to inhibit the activity of squalene synthase. They can not only prevent and inhibit the development and progression of arteriosclerosis but can also inhibit thrombosis in arteriosclerotic lesions and can improve hemodynamics.

  式(I)化合物： 其中R1代表通过环碳原子连接到 A 所代表的键或基团上的饱和杂环基团；R2a、R2b、R2c、R3a、R3b、R3c 和 R3d 是氢或各种其他基团或原子；A 代表单键或具有 1 至 6 个碳原子的亚烷基]是血清素 2 受体拮抗剂，具有抑制角鲨烯合成酶活性的能力。它们不仅能预防和抑制动脉硬化的发生和发展，还能抑制动脉硬化病变部位的血栓形成，并能改善血液动力学。
• Peroxides, their preparation process and use
  申请人：——

  公开号：US20030073861A1

  公开（公告）日：2003-04-17

  The invention relates to a preparation process for making peroxy esters and peroxy carbonates, peroxy ester peroxy carbonates, mixed diperoxides, mixed diperoxy esters, and mixed diperoxy carbonates, and to specific monoperoxy esters, monoperoxy carbonates, mixed peroxides, mixed diperoxy esters, mixed diperoxy carbonates, peroxy ester peroxy carbonates, and mixtures thereof. The process involves the reaction of a type-3 ketone peroxide with a reactive carbonyl compound and optional subsequent reaction with an alkyl vinyl ether, acetal, halogen formate, or carboxylic acid anhydride.

  本发明涉及一种制备过氧化酯和过氧化碳酸盐、过氧化酯过氧化碳酸盐、混合二过氧化物、混合二过氧化酯和混合二过氧化碳酸盐的制备工艺，以及特定的单过氧化酯、单过氧化碳酸盐、混合过氧化物、混合二过氧化酯、混合二过氧化碳酸盐、过氧化酯过氧化碳酸盐及其混合物。该工艺涉及 3 型过氧化酮与活性羰基化合物的反应，以及随后与烷基乙烯基醚、缩醛、甲酸卤素酯或羧酸酐的任选反应。
• Ketone peroxide derivatives, their preparation and use
  申请人：——

  公开号：US20040260111A1

  公开（公告）日：2004-12-23

  The invention relates to peroxides derivable from 1 The invention further relates to the process to make these peroxides as well as to their use in polymerization, curing, and modification reactions.

  本发明涉及可由以下物质衍生的过氧化物 1 本发明还涉及制造这些过氧化物的工艺以及它们在聚合、固化和改性反应中的用途。