2-Propenamide, 2-methyl-N-1-piperidinyl- | 918637-95-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 2-Propenamide, 2-methyl-N-1-piperidinyl-
• 英文别名: 2-methyl-N-piperidin-1-ylprop-2-enamide
• CAS: 918637-95-3
• 化学式: C₉H₁₆N₂O
• 分子量: 168.239
• InChiKey: ACOJZELIHWWTFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  32.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Propenamide, 2-methyl-N-1-piperidinyl- 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) sodium hydride 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 29.0h， 生成 3-Methyl-1-(piperidin-1-yl)-1,5-dihydro-2H-pyrrol-2-one
  参考文献：
  名称：

  Synthesis of Cyclic Enehydrazides by Ring-Closing Metathesis

  摘要：

  通过闭环偏析（RCM）反应，从前驱体二烯肼有效地制备了一系列五元和六元不饱和肼。通过对适当的肼进行连续的酰化和烷基化反应，很容易得到母体化合物。

  DOI：

  10.1055/s-2006-949464
• 作为产物：
  描述：

  1-氨基哌啶 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以90%的产率得到2-Propenamide, 2-methyl-N-1-piperidinyl-
  参考文献：
  名称：

  Synthesis of Cyclic Enehydrazides by Ring-Closing Metathesis

  摘要：

  通过闭环偏析（RCM）反应，从前驱体二烯肼有效地制备了一系列五元和六元不饱和肼。通过对适当的肼进行连续的酰化和烷基化反应，很容易得到母体化合物。

  DOI：

  10.1055/s-2006-949464

文献信息

• Micelles For Drug Delivery
  申请人：Yang Yi-Yan

  公开号：US20100159019A1

  公开（公告）日：2010-06-24

  The invention provides a block copolymer comprising at least a first block and a second block. The first block comprises a plurality of temperature-sensitive monomeric units, a plurality of hydrophilic monomeric units and a plurality of targeting monomeric units, and the second block comprises a plurality of hydrophobic monomeric units. The second block comprises at least one pH-sensitive moiety.

  本发明提供了一种嵌段共聚物，包括至少第一嵌段和第二嵌段。第一嵌段包括多个温度敏感单体单元、多个亲水性单体单元和多个定位单体单元，第二嵌段包括多个疏水性单体单元。第二嵌段包括至少一个pH敏感基团。
• DISPERSED COMPOSITION, POLYMERIZABLE COMPOSITION, LIGHT SHIELDING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, LIQUID CRYSTAL DISPLAY DEVICE, WAFER-LEVEL LENS, AND IMAGING UNIT
  申请人：FUJIFILM Corporation

  公开号：EP2354187A1

  公开（公告）日：2011-08-10

  A dispersion composition is provided in which the dispersibility of titanium black is high, the sedimentation of titanium black over time is suppressed, and overall dispersibility and storage stability are high. Further, a polymerizable composition is provided in which favorable coating property on a substrate and even film thickness can be obtained, generation of residue in an unexposed region when a pattern is formed can be suppressed, and favorable pattern shape having any steps after exposure/development can be obtained. The dispersion composition contains (A) titanium black, (B) a graft copolymer and (C) a solvent.

  本发明提供了一种分散组合物，其中钛黑的分散性高，可抑制钛黑随时间的沉淀，整体分散性和储存稳定性高。此外，本发明还提供了一种可聚合组合物，可获得良好的基底涂层性能和均匀的膜厚，可抑制图案形成时未曝光区域残留物的产生，并可获得曝光/显影后具有任何步骤的良好图案形状。分散组合物包含 (A) 钛黑、(B) 接枝共聚物和 (C) 溶剂。
• DISPERSION COMPOSITION, PHOTOSENSITIVE RESIN COMPOSITION, AND SOLID-STATE IMAGE PICKUP ELEMENT
  申请人：FUJIFILM Corporation

  公开号：EP2502963A1

  公开（公告）日：2012-09-26

  A photosensitive resin composition which can form a pattern attaining high resolution and having a high refractive index and a high transmittance is provided. The photosensitive resin composition includes a dispersion composition including (A) titanium dioxide particles having an average primary particle diameter of from 1 nm to 100 nm, (B) a graft copolymer that has a graft chain having a number of atoms other than hydrogen atoms in a range of from 40 to 10,000 and (C) a solvent, and (D) a polymerizable compound, and (E) a polymerization initiator.

  本发明提供了一种光敏树脂组合物，该组合物可形成具有高分辨率、高折射率和高透光率的图案。该光敏树脂组合物包括一种分散组合物，其中包括：(A) 二氧化钛颗粒，其平均主颗粒直径为 1 纳米至 100 纳米；(B) 接枝共聚物，其接枝链中氢原子以外的原子数在 40 至 10,000 之间；(C) 溶剂；(D) 可聚合化合物；(E) 聚合引发剂。
• OPTICAL MEMBER SET AND SOLID-STATE IMAGE PICKUP ELEMENT USING SAME
  申请人：FUJI-FILM Corporation

  公开号：EP2799912A1

  公开（公告）日：2014-11-05

  An optical member set which has a first optical member formed by curing a curable resin composition, and a second optical member which is covered by the first optical member, in which the first optical member has a refractive index of 1.25 to 1.45 and the second optical member has a refractive index of 1.65 to 1.95.

  一种光学元件组，它具有通过固化可固化树脂组合物形成的第一光学元件和被第一光学元件覆盖的第二光学元件，其中第一光学元件的折射率为 1.25 至 1.45，第二光学元件的折射率为 1.65 至 1.95。
• OPTICAL MEMBER SET AND SOLID-STATE IMAGE SENSOR USING SAME
  申请人：FUJI-FILM Corporation

  公开号：EP2799913A1

  公开（公告）日：2014-11-05

  An optical member set which has a first optical member formed by curing a composition of curable resins, and a second optical member which is covered by the first optical member, in which the contact angle with water on a surface, which comes into contact with a first optical member, of the second optical member is 70 to 97° and the contact angle with the water on a surface of the opposite side to the side, which comes into contact with the second optical member, of the first optical member is 80 to 115°.

  一种光学元件组，它具有通过固化可固化树脂组合物形成的第一光学元件，以及被第一光学元件覆盖的第二光学元件，其中第二光学元件与第一光学元件接触的表面与水的接触角为 70 至 97°，而与第一光学元件接触的第二光学元件相反一侧表面与水的接触角为 80 至 115°。