Acrylsaeure-tritylester | 14989-78-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: Acrylsaeure-tritylester
• 英文别名: Triphenylmethylacrylat；triphenylmethyl acrylate；trityl prop-2-enoate
• CAS: 14989-78-7
• 化学式: C₂₂H₁₈O₂
• 分子量: 314.384
• InChiKey: MTAHZRMCRJONNA-UHFFFAOYSA-N

物化性质

• 沸点：
  424.0±14.0 °C(Predicted)
• 密度：
  1.119±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三苯基氯甲烷 、 丙烯酸钾 、 对苯二酚 在 氯化钾 、 triphenyl methyl acrylate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 Acrylsaeure-tritylester
  参考文献：
  名称：

  Binder for anti-fouling paints

  摘要：

  一种防污海洋涂料包括颜料，海洋生物杀菌剂，该杀菌剂可能与颜料相同或不同，以及一种成膜粘合剂，该成膜粘合剂是一种可水解的聚合物，其中含有以下结构单元：##STR1## 并可通过聚合具有以下结构式的α-芳基烷基酯获得：##STR2## 其中R是α，β-不饱和有机基团，每个Ar独立是芳基基团，而R'是氢原子或烷基或芳基基团。

  公开号：

  US04752629A1

文献信息

• ALPHA-SUBSTITUTED ACRYLATE ESTERS, COMPOSITION CONTAINING THEREOF, AND METHOD FOR PRODUCING THOSE
  申请人：Kawamoto Takahiro

  公开号：US20130072712A1

  公开（公告）日：2013-03-21

  A method for producing α-substituted acrylate esters is provided which can be suitably used as an industrial method for producing α-substituted acrylate esters because the method does not have problems of apparatus corrosion or does not require waste detoxification and allows reaction in a short time with high yield. The method for producing an α-substituted acrylate ester includes a step of carrying out a reaction of a compound having a specific structure and an active hydrogen-containing compound under a condition where a tertiary amine and an acid and/or a salt thereof coexist.

  提供了一种生产α-取代丙烯酸酯的方法，该方法可适当用作工业生产α-取代丙烯酸酯的方法，因为该方法不存在设备腐蚀问题或不需要废物解毒，并允许在短时间内高产率反应。生产α-取代丙烯酸酯的方法包括在三级胺和酸和/或其盐共存的条件下，进行具有特定结构和含有活性氢的化合物的反应的步骤。
• Coating Composition, Optical Film, Antireflective, Film, Polarizing Plate, And Display Device Using The Same
  申请人：Yoshizawa Masataka

  公开号：US20080038561A1

  公开（公告）日：2008-02-14

  There is provided a coating composition capable of improving evenness in drying and evenness in airing and causing no impairment of evenness in coating, which is useful for an antireflective film having high uniformity in surface conditions and attaining sufficient antireflection performance and for a polarizing plate and a display device each using such an antireflective film. As the coating composition as mentioned above, a coating composition including a fluoroaliphatic group-containing copolymer that includes a repeating unit corresponding to the fluoroaliphatic group-containing monomer represented by the following formula (1) and a repeating unit corresponding to the monomer represented by the following formula (2) was found: in formula [1], R 0 represents a hydrogen atom, a halogen atom or a methyl group; L represents a divalent linkage group; and n represents an integer of 1 to 18, and in formula [2], R 11 represents a hydrogen atom, a halogen atom or a methyl group; L 11 represents a divalent linkage group; and R 13 , R 14 and R 15 each represents a 1-20C linear, branched or cyclic alkyl group which may have a substituent.

  提供了一种涂层组合物，能够提高干燥均匀性和通风均匀性，且不会影响涂层均匀性，该组合物对于具有高表面条件均匀性和达到足够抗反射性能的抗反射膜以及使用此类抗反射膜的偏光板和显示装置非常有用。作为上述涂层组合物，发现包括重复单元对应于以下公式（1）所表示的含氟脂肪基单体的含氟脂肪基共聚物和对应于以下公式（2）所表示的单体的重复单元的涂层组合物：在公式[1]中，R0表示氢原子、卤素原子或甲基基团；L表示双价连接基团；n表示1到18的整数，在公式[2]中，R11表示氢原子、卤素原子或甲基基团；L11表示双价连接基团；R13、R14和R15分别表示1-20C线性、支链或环状烷基，可以有取代基。
• THERMOPLASTIC POLYMER COMPOSITION AND MOLDED PRODUCT
  申请人：MAWATARI Masaaki

  公开号：US20120065332A1

  公开（公告）日：2012-03-15

  A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.

  一种热塑性聚合物组合物，能够表现出优异的抗冲击性、耐久性和除静电性，包含（A）50至95重量％的脂肪族聚酯基树脂和（B）5至50重量％的嵌段共聚物，其中（B1）是具有聚酰胺、聚酯、聚烯烃或聚氨酯中至少一种的硬段块，（B2）是具有醚键的软段块。
• Process for preparing triarylmethyl methacrylate
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0134005A2

  公开（公告）日：1985-03-13

  Abstract of the Disclosure A triarylmethyl methacrylate is produced by reacting methacrylic acid with a triarylmethylating agent in an inert, organic solvent containing therein an excess amount of an amine or in the presence of an anion exchanger.

  公开内容摘要 甲基丙烯酸三芳基甲基酯是在含有过量胺的惰性有机溶剂中或在阴离子交换剂存在下，通过甲基丙烯酸与三芳基甲基化剂反应制得的。
• Olefin block copolymer and method of producing same
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0462588A2

  公开（公告）日：1991-12-27

  An olefin block copolymer comprising the following segment A: and the following segment B: bonded in block, and the Q value of the segment A is at most 3.5, the Q value of the segment B is at most 4.0, and the amount of the segment B is at least 5 wt%, wherein R¹ represents a hydrogen atom or an alkyl group of 1-12 carbon atoms, R² represents a hydrogen atom or an alkyl group of 1-6 carbon atoms, R³ represents a hydrocarbon residue of 1-18 carbon atoms, m is an integer 70 or more, and n is an integer 50 or more. This block copolymer is manufactured by the two stages of polymerization of ethylene and acylic acid or the ester thereof using a catalyst comprising a lithium compound containing a cyclopentadienyl group, an alkaline metal compound bearing aklyl or aryl groups, and a halide of a lanthanide series of metal or yttrium.

  一种烯烃嵌段共聚物，由以下 A 部分组成 和以下 B 部分 其中 R¹ 代表氢原子或 1-12 个碳原子的烷基，R² 代表氢原子或 1-6 个碳原子的烷基，R³ 代表 1-18 个碳原子的烃残基，m 为 70 以上的整数，n 为 50 以上的整数。 这种嵌段共聚物是通过乙烯和丙烯酸或其酯的两阶段聚合反应制造的，使用的催化剂包括含环戊二烯基的锂化合物、含烷基或芳基的碱金属化合物和镧系金属或钇的卤化物。