4-cyano-3-fluorophenyl 4-(4-pentylbenzoyloxy)-2-fluorobenzoate | 1210887-74-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-cyano-3-fluorophenyl 4-(4-pentylbenzoyloxy)-2-fluorobenzoate
• 英文别名: (4-Cyano-3-fluorophenyl) 2-fluoro-4-(4-pentylbenzoyl)oxybenzoate
• CAS: 1210887-74-3
• 化学式: C₂₆H₂₁F₂NO₄
• 分子量: 449.454
• InChiKey: IAXXWXWWHGSLCR-UHFFFAOYSA-N

物化性质

• 沸点：
  594.2±50.0 °C(Predicted)
• 密度：
  1.29±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  33
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-戊基苯甲酰氯 在 吡啶 、 草酰氯 、 palladium 10% on activated carbon 、 氢气 、 N,N-二甲基甲酰胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 6.0h， 生成 4-cyano-3-fluorophenyl 4-(4-pentylbenzoyloxy)-2-fluorobenzoate
  参考文献：
  名称：

  Synthesis of Fluorosubstituted Three Ring Esters and Their Dielectric Properties

  摘要：

  Laterally substituted by fluorine atoms 4-cyanophenyl 4-(4-pentylbenzoyloxy)-benzoates have been prepared and their phase transition temperatures, enthalpies and dielectric properties upon frequency were evaluated. The novel compounds exhibit a broad range of nematic mesophase, large positive dielectric anisotropy changing sign at low frequency. They are convenient components of LC mixtures for dual frequency addressing devices.

  DOI：

  10.1080/15421400902817361

文献信息

• Liquid Crystals Composition and Liquid Crystal Display with Patterned Electrodes
  申请人：Gauza Sebastian

  公开号：US20110075074A1

  公开（公告）日：2011-03-31

  A blue phase liquid crystal composition and a LC display using the composition. The liquid crystal composition includes a first class including a highly polar compound and a second class including a highly conjugated liquid crystal compound. The blue phase liquid crystal display device includes first and second substrates each with polarizer on the exterior surface and the blue phase liquid crystal composition sandwiched therebetween with and patterned electrodes on one of the substrates or both substrates. The patterned electrodes can be T-shaped, chevron or v-shaped, thin comb like shape and can also be flat or trapezoidal. The device outputs different light transmissions from the electrically controllable induced birefringence of the blue phase LC material for a low driving voltage, high transmittance blue phase liquid crystal display device.
• US8377331B2
  申请人：——

  公开号：US8377331B2

  公开（公告）日：2013-02-19