Fe(N2)(tris[2-(dimethylphosphino)ethyl]phosphine) | 198192-23-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Fe(N2)(tris[2-(dimethylphosphino)ethyl]phosphine)
• 英文别名: iron;molecular nitrogen;tris(2-dimethylphosphanylethyl)phosphane
• CAS: 198192-23-3
• 化学式: C₁₂H₃₀FeN₂P₄
• 分子量: 382.126
• InChiKey: CUPHZFRZDCKYBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  乙醇 、 四苯硼钠 、 Fe(N2)(tris[2-(dimethylphosphino)ethyl]phosphine) 以 乙醇 为溶剂， 以37%的产率得到[FeH(P(CH2CH2PMe2)3N]2(tetraphenylborate)2
  参考文献：
  名称：

  Field, Leslie D.; Messerle, Barbara A.; Smernik, Ronald J., Inorganic Chemistry, 1997, vol. 36, # 26, p. 5984 - 5990

  摘要：

  DOI：
• 作为产物：
  描述：

  [FeH(N2)(tris[2-(dimethylphosphino)ethyl]phosphine)]BPh4 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以67%的产率得到Fe(N2)(tris[2-(dimethylphosphino)ethyl]phosphine)
  参考文献：
  名称：

  Field, Leslie D.; Messerle, Barbara A.; Smernik, Ronald J., Inorganic Chemistry, 1997, vol. 36, # 26, p. 5984 - 5990

  摘要：

  DOI：

文献信息

• Mixed-Valence Dinitrogen-Bridged Fe(0)/Fe(II) Complex
  作者：Leslie D. Field、Ruth W. Guest、Peter Turner

  DOI：10.1021/ic101646p

  日期：2010.10.4

  The reactions of a dinitrogen-bridged Fe(II)/Fe(II) complex [(FeH(PP3))(2)(mu-N-2)](2+) (3) (PP3 = P(CH2CH2PMe2)(3)) with base were investigated usin N-15 labeling techniques to enhance characterization. In the presence of base, 3 is initially deprotonated to the Fe(II)/Fe(0) dinitrogen-bridged complex [(FeH(PP3))(kt-N-2)(Fe(PP3))]' (4) and then to the symmetrical Fe(0)/Fe(0) dinilrogen-bridged complex (Fe(PP3))(2)(u-N-2) (5). [(FeH(PP3))(j4-N2)(Fe(PP3))](+) (4) exhibits unusual long-range 31P-31P NMR coupling through the bridging dinitrogen ligand from the phosphines at the Fe(0) center and those at the Fe(II) center. Reaction of 4 with base under an atmosphere of argon resulted in the known dinitrogen Fe(0) complex Fe(N-2)(PP3) (6) and a solvent C H activation product. Complexes 3, 4, and 5 were fully characterized by multinuclear NMR spectroscopy, and complexes 3 and 4 by X-ray crystallography.