bis(O,O'-didodecylthiophosphoryl)disulfide | 7539-14-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: bis(O,O'-didodecylthiophosphoryl)disulfide
• 英文别名: (Didodecoxyphosphinothioyldisulfanyl)-didodecoxy-sulfanylidene-lambda5-phosphane；(didodecoxyphosphinothioyldisulfanyl)-didodecoxy-sulfanylidene-λ5-phosphane
• CAS: 7539-14-2
• 化学式: C₄₈H₁₀₀O₄P₂S₄
• 分子量: 931.531
• InChiKey: GSPXAMCZYIMKAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.6
• 重原子数：
  58
• 可旋转键数：
  51
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  152
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  bis(O,O'-didodecylthiophosphoryl)disulfide 、 重氮甲烷 以 乙醚 为溶剂， 以84%的产率得到Dithiophosphoric acid S-(bis-dodecyloxy-thiophosphorylsulfanylmethyl) ester O,O'-didodecyl ester
  参考文献：
  名称：

  Khaskin, B. A.; Sheluchenko, O. D.; Torgasheva, N. A., Journal of general chemistry of the USSR, 1980, vol. 50, # 9, p. 1606 - 1609

  摘要：

  DOI：

文献信息

• Shamrock surfactants and their methods of use
  申请人：Jaeger A. David

  公开号：US20070185006A1

  公开（公告）日：2007-08-09

  Disclosed are surfactants that contain two ionic or polar nonionic head groups, each connected to a central ionic head group by a hydrocarbon linking moiety. The central head group is a dithiophosphate, dithiocarbamate, or quaternary ammonium group. These surfactants have potential applications in chemical decontamination of mustard (simulants), storage and release devices/chemical switches and the remediation of heavy-metal ion-contaminated water.

  本发明涉及一种表面活性剂，其包含两个离子性或极性非离子性头基，每个头基通过一个烃链连接基团连接到一个中心离子性头基。中心头基是二硫代磷酸盐、二硫代氨基甲酸盐或季铵基团。这些表面活性剂在芥末（模拟物）化学去污、储存和释放装置/化学开关以及重金属离子污染水的修复方面具有潜在应用。
• Khaskin, B. A.; Sheluchenko, O. D.; Torgasheva, N. A., Journal of general chemistry of the USSR, 1988, vol. 58, # 5, p. 923 - 928
  作者：Khaskin, B. A.、Sheluchenko, O. D.、Torgasheva, N. A.、Ishmuratov, A. S.

  DOI：——

  日期：——
• Synthesis and characterization of liquid platinum compounds
  作者：Michel Gianini、Walter R. Caseri、Volker Gramlich、Ulrich W. Suter

  DOI：10.1016/s0020-1693(99)00499-5

  日期：2000.3

  Liquid platinum complexes were obtained with a ligand with alkyl chains that attach to the coordination plane perpendicularly and herewith render a close packing of the molecules difficult for certain chain lengths. Bis(O, O'-dialkyldithiophosphato)platinum(II) complexes, Pt(C(x)dtp)(2) where the alkyl chains are methyl (x = 1), ethyl (x = 2), propyl (x = 3), butyl (x = 4), pentyl (x = 5), hexyl (x = 6), heptyl (x = 7), dodecyl (x = 12), and octadecyl (x = 18), were investigated. The platinum compounds were synthesized via two routes: reaction of tetrachloroplatinate(IT) with ammonium-O,O'-dialkyldithiophosphates or oxidative addition of (O,O'-dialkylthiophosphoryl)disulfides to tris(styrene)platinum(0). The melting temperatures as a function of the alkyl chain length show a minimum for the complex with pentyl groups. The complexes with pentyl and hexyl groups are liquid at room temperature, and the complexes with butyl and heptyl groups melt only slightly above room temperature. Depending on the complex, the low melting temperatures are induced by an unfavorable packing of the molecules in the solid state, reflected in a low melting enthalpy, or melting entropy. The molecular weights of the liquid complexes are between 700 and 800 and, therefore, extraordinarily high for liquid metal compounds. Depending on the alkyl groups, the complexes decompose at 172-241 degrees C. Crystals of bis(O,O'-diethyldithiophosphato)platinum(II), Pt(C(2)dtp)(2), are monoclinic, space group P2(1)/n, a = 8.90, b = 8.70, c = 12.45 Angstrom, alpha = gamma = 90 degrees, beta = 100.89 degrees, and Z = 4. (C) 2000 Elsevier Science S.A. All rights reserved.
• XASKIN B. A.; SHELUCHENKO O. D.; TORGASHEVA N. A.; PROMONENKOV V. K., ZH. OBSHCH. XIMII, 1980, 50, HO 9, 1390-1394
  作者：XASKIN B. A.、 SHELUCHENKO O. D.、 TORGASHEVA N. A.、 PROMONENKOV V. K.

  DOI：——

  日期：——
• XASKIN, B. A.;SHELUCHENKO, O. D.;TORGASHEVA, N. A.;ISHMURATOV, A. S., ZH. OBSHCH. XIMII, 58,(1988) N 5, 1041-1046
  作者：XASKIN, B. A.、SHELUCHENKO, O. D.、TORGASHEVA, N. A.、ISHMURATOV, A. S.

  DOI：——

  日期：——