Methanol, cadmium salt | 21350-44-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Methanol, cadmium salt
• 英文别名: Dimethoxycadmium
• CAS: 21350-44-7
• 化学式: C₂H₆CdO₂
• 分子量: 174.478
• InChiKey: SSIANRKLOXEQTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.03
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.06
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Methanol, cadmium salt 、 diborane(6) 以 四氢呋喃 为溶剂， 生成 cadmium tetrahydroborate
  参考文献：
  名称：

  Wiberg, E.; Henle, W., Zeitschrift fur Naturforschung, 1952, vol. 7b, p. 582

  摘要：

  DOI：
• 作为产物：
  描述：

  生成 Methanol, cadmium salt
  参考文献：
  名称：

  Reactions of Cd(OAc)2·2H2O with variously substituted pyridines. Efforts to unravel the factors that determine structure/nuclearity of the products

  摘要：

  The reactions of Cd(OAc)(2)center dot 2H(2)O with variously substituted pyridines in methanol afforded unique one-dimensional coordination polymers (1D CPs), [Cd-2(mu(2)-kappa(2):kappa(1)-OAc)(2)(mu(2)-kappa(1):kappa(1)-OAc)(2)L-2] (L= NC5H5 (1), NC5H4Me-3 (2), and NC5H3Me2-3,5 (3)) and [Cd-3(mu(3)-kappa(1):kappa(2)-OAc)(3)(mu(2)-kappa(2):kappa(1)-OAc)(2)(NC5H3Me2-3,4)(2)] (4), and discrete and bimolecular complexes, [(Cd(OAc)(2)(NC5H3Me2-3,4)(2)(H2O)(2)] (5), [Cd(kappa 2-OAc)(2)(NC5H4Me-4)(2)(H2O)]center dot[Cd(kappa 2-OAc)(2)(H2O)(2))] (6), [Cd(kappa(2)-OAc)(2)L2L']center dot xH(2)O (x = 0, L' = H2O, L = NC5H4 (OMe)-4 (7); (NC5H4Bu)-Bu-t-4 (8); x = 2, L = L' = NC5H4(NMe2)-4 (9 center dot 2H(2)O)). The products were characterised by elemental analysis, IR, solution NMR (H-1 and C-13), solid-state CP-MAS C-13{H-1} and Cd-113 NMR, TGA/DTA analyses, and single crystal X-ray diffraction. Phase purity of 1-4 was verified by powder Xray diffraction (PXRD). Plausible mechanisms of formation of the products are proposed based on a point zero charge model. 4 represents the first cadmium containing 1D CP that possesses a tridentate bridging (mu(3)-kappa(1):kappa(2)) acetate coordination mode and 6 represents the first structurally characterised bimolecular cadmium(II) complex containing two different neutral cadmium(II) coordination species per formula unit. 9 center dot 2H(2)O was calcined at 500 degrees C to afford CdO as confirmed by PXRD and the morphology of CdO was studied by scanning electron microscopy. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.06.002

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44
  作者：

  DOI：——

  日期：——
• Banait, J S; Singh, Baljit, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1991, vol. 30, # 10, p. 895 - 897
  作者：Banait, J S、Singh, Baljit

  DOI：——

  日期：——
• Reactions of Cd(OAc)2·2H2O with variously substituted pyridines. Efforts to unravel the factors that determine structure/nuclearity of the products
  作者：Priya Saxena、Natesan Thirupathi

  DOI：10.1016/j.poly.2015.06.002

  日期：2015.9

  The reactions of Cd(OAc)(2)center dot 2H(2)O with variously substituted pyridines in methanol afforded unique one-dimensional coordination polymers (1D CPs), [Cd-2(mu(2)-kappa(2):kappa(1)-OAc)(2)(mu(2)-kappa(1):kappa(1)-OAc)(2)L-2] (L= NC5H5 (1), NC5H4Me-3 (2), and NC5H3Me2-3,5 (3)) and [Cd-3(mu(3)-kappa(1):kappa(2)-OAc)(3)(mu(2)-kappa(2):kappa(1)-OAc)(2)(NC5H3Me2-3,4)(2)] (4), and discrete and bimolecular complexes, [(Cd(OAc)(2)(NC5H3Me2-3,4)(2)(H2O)(2)] (5), [Cd(kappa 2-OAc)(2)(NC5H4Me-4)(2)(H2O)]center dot[Cd(kappa 2-OAc)(2)(H2O)(2))] (6), [Cd(kappa(2)-OAc)(2)L2L']center dot xH(2)O (x = 0, L' = H2O, L = NC5H4 (OMe)-4 (7); (NC5H4Bu)-Bu-t-4 (8); x = 2, L = L' = NC5H4(NMe2)-4 (9 center dot 2H(2)O)). The products were characterised by elemental analysis, IR, solution NMR (H-1 and C-13), solid-state CP-MAS C-13H-1} and Cd-113 NMR, TGA/DTA analyses, and single crystal X-ray diffraction. Phase purity of 1-4 was verified by powder Xray diffraction (PXRD). Plausible mechanisms of formation of the products are proposed based on a point zero charge model. 4 represents the first cadmium containing 1D CP that possesses a tridentate bridging (mu(3)-kappa(1):kappa(2)) acetate coordination mode and 6 represents the first structurally characterised bimolecular cadmium(II) complex containing two different neutral cadmium(II) coordination species per formula unit. 9 center dot 2H(2)O was calcined at 500 degrees C to afford CdO as confirmed by PXRD and the morphology of CdO was studied by scanning electron microscopy. (C) 2015 Elsevier Ltd. All rights reserved.
• Wiberg, E.; Henle, W., Zeitschrift fur Naturforschung, 1952, vol. 7b, p. 582
  作者：Wiberg, E.、Henle, W.

  DOI：——

  日期：——