disilver;2,2,3,3,3-pentafluoropropanoate;trimethylphosphane | 198564-17-9

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: disilver;2,2,3,3,3-pentafluoropropanoate;trimethylphosphane
• CAS: 198564-17-9
• 化学式: C₁₂H₁₈Ag₂F₁₀O₄P₂
• 分子量: 693.94
• InChiKey: LTROKAAWHKBODA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  disilver;2,2,3,3,3-pentafluoropropanoate;trimethylphosphane 以 neat (no solvent) 为溶剂， 生成 银
  参考文献：
  名称：

  Thermal and spectroscopic studies of Ag(I) complexes with trimethylphosphine and perfluorinated carboxylates

  摘要：

  Silver(I) complexes with trimethylphosphine and perfluorinated carboxylates of the general formula [Me3PAgOOCR](2), where R = C2F5, C3F7, C6F13, C7F15, C8F17, C9F19, C6F5 and Me3PAgOOC(CF2)(3) have been prepared and their thermal decomposition studied. Thermal decomposition proceeded in multistages, starting with the detachment of carboxylates and followed by trimethylphosphine dissociation. The final product was metallic silver. The temperatures of silver formation were in the 473-633 K range. Complexes were characterised by C-13, F-19, P-31 NMR and vibrational spectra. Spectral analysis favoured Ag(I) trigonal coordination with unidentate trimethylphosphine and bidentate carboxylates forming bridges between silver(I) ions. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(97)00233-5
• 作为产物：
  描述：

  silver(I) pentafluoropropionate 、 三甲基膦 以 四氢呋喃 、 乙醇 为溶剂， 生成 disilver;2,2,3,3,3-pentafluoropropanoate;trimethylphosphane
  参考文献：
  名称：

  Thermal and spectroscopic studies of Ag(I) complexes with trimethylphosphine and perfluorinated carboxylates

  摘要：

  Silver(I) complexes with trimethylphosphine and perfluorinated carboxylates of the general formula [Me3PAgOOCR](2), where R = C2F5, C3F7, C6F13, C7F15, C8F17, C9F19, C6F5 and Me3PAgOOC(CF2)(3) have been prepared and their thermal decomposition studied. Thermal decomposition proceeded in multistages, starting with the detachment of carboxylates and followed by trimethylphosphine dissociation. The final product was metallic silver. The temperatures of silver formation were in the 473-633 K range. Complexes were characterised by C-13, F-19, P-31 NMR and vibrational spectra. Spectral analysis favoured Ag(I) trigonal coordination with unidentate trimethylphosphine and bidentate carboxylates forming bridges between silver(I) ions. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(97)00233-5