N,N,3,5-tetramethyl-2-(trimethylsilyl)borinin-1(2H)-amine | 300362-34-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N,N,3,5-tetramethyl-2-(trimethylsilyl)borinin-1(2H)-amine
• CAS: 300362-34-9
• 化学式: C₁₂H₂₄BNSi
• 分子量: 221.226
• InChiKey: HEYJTBRLIZEBOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.21
• 重原子数：
  15.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  3.01
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  N,N,3,5-tetramethyl-2-(trimethylsilyl)borinin-1(2H)-amine 以 二氯甲烷 、 甲苯 为溶剂， 生成 2-(3,5-Dimethyl-1-boranuidacyclohexa-1,3,5-trien-1-yl)-1,3,4,5-tetramethylimidazol-1-ium
  参考文献：
  名称：

  Borabenzene Derivatives. 33. 3,5-Dimethylborabenzene 1,3,4,5-Tetramethylimidazol-2-ylidene:  The First Carbene Adduct of a Borabenzene¹

  摘要：

  The stable carbene 1,2,3,5-tetramethylimidazol-2-ylidene forms an, adduct with 3,5-dimethylborabenzene. This adduct 8 can readily be made from the carbene and 1-chloro-3,5-dimethyl-2-(trimethylsilyl)-1,2-dihydroborinine (6) as colorless crystals. The structure of 8 is closer to that of the anion in NMe3Ph(C5H5BMe) (9) than to the structures of known betainic adducts. There is no noticeable conjugation between the borabenzene and the imidazol-2-ylidene moieties.

  DOI：

  10.1021/om000532o
• 作为产物：
  描述：

  三甲基氯硅烷 、 lithium 1-(dimethylamino)-3,5-dimethylboratabenzene 以 四氢呋喃 为溶剂， 以86%的产率得到N,N,3,5-tetramethyl-2-(trimethylsilyl)borinin-1(2H)-amine
  参考文献：
  名称：

  Borabenzene Derivatives. 33. 3,5-Dimethylborabenzene 1,3,4,5-Tetramethylimidazol-2-ylidene:  The First Carbene Adduct of a Borabenzene¹

  摘要：

  The stable carbene 1,2,3,5-tetramethylimidazol-2-ylidene forms an, adduct with 3,5-dimethylborabenzene. This adduct 8 can readily be made from the carbene and 1-chloro-3,5-dimethyl-2-(trimethylsilyl)-1,2-dihydroborinine (6) as colorless crystals. The structure of 8 is closer to that of the anion in NMe3Ph(C5H5BMe) (9) than to the structures of known betainic adducts. There is no noticeable conjugation between the borabenzene and the imidazol-2-ylidene moieties.

  DOI：

  10.1021/om000532o