2-chloro-4,5-bis(trifluoromethyl)-1,3,2-diazastibazole | 288586-35-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 2-chloro-4,5-bis(trifluoromethyl)-1,3,2-diazastibazole
• 英文别名: 2-Chloro-4,5-bis(trifluoromethyl)-1,3,2-diazastibole
• CAS: 288586-35-6
• 化学式: C₄ClF₆N₂Sb
• 分子量: 347.251
• InChiKey: ZCRLHKPTRTVCSL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.23
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  dichlorodimethylaminostibane 、 1,1,1,4,4,4,-hexafluoro-2,3-butanediimine 在 1-甲基吡咯烷 作用下， 以 乙醚 为溶剂， 生成 2-chloro-4,5-bis(trifluoromethyl)-1,3,2-diazastibazole
  参考文献：
  名称：

  Carbon–carbon bond formation in the reductive coupling of trifluoroacetonitrile and pentafluorobenzonitrile – synthetic routes to new perfluoroalkyl- and perfluoroaryl-substituted α-diimines: versatile synthons for heterocycle synthesis

  摘要：

  Reductive coupling of perfluoroalkyl- and perfluoroaryl-nitriles with [(eta(5)-C5H5)(2)TiCl](2) provides the corresponding mu-diiminatodititanium complexes. Protonolysis of the Ti-N bonds with ethereal HCl liberates the corresponding perfluoroalkyl- and perfluoroaryl-substituted alpha-dimimes, two of which have been fully characterized by IR, H-1 and C-13 NMR, and X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.002

文献信息

• Carbon–carbon bond formation in the reductive coupling of trifluoroacetonitrile and pentafluorobenzonitrile – synthetic routes to new perfluoroalkyl- and perfluoroaryl-substituted α-diimines: versatile synthons for heterocycle synthesis
  作者：Bruce N. Diel、Peter J. Deardorff、Catherine M. Zelenski、Christopher Incarvito、Louise Liable-Sands、Arnold M. Rheingold

  DOI：10.1016/j.ica.2004.09.002

  日期：2004.11

  Reductive coupling of perfluoroalkyl- and perfluoroaryl-nitriles with [(eta(5)-C5H5)(2)TiCl](2) provides the corresponding mu-diiminatodititanium complexes. Protonolysis of the Ti-N bonds with ethereal HCl liberates the corresponding perfluoroalkyl- and perfluoroaryl-substituted alpha-dimimes, two of which have been fully characterized by IR, H-1 and C-13 NMR, and X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.