Pt(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithiolate(2-))(diethylsulfide)2 | 181217-75-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: Pt(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithiolate(2-))(diethylsulfide)2
• CAS: 181217-75-4
• 化学式: C₁₆H₂₄PtS₁₀
• 分子量: 732.107
• InChiKey: DUEKCTSALDLLAF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.42
• 重原子数：
  27.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  Pt(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithiolate(2-))(diethylsulfide)2 以 硝基苯 为溶剂， 生成 [Pt(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithiolate(2-))(diethylsulfide)]n
  参考文献：
  名称：

  Preparation and properties of C8H4S8-platinum(II) complexes and electrical conductivities of their oxidized species and X-ray crystal structure of C8H4S8(CH2CH2CN)2 as a pro-ligand compound

  摘要：

  Using the C8H4S82- ligand [2-{(4,5-ethylenedithio)-1,3-dithiole-2-ylidiene}-1,3-dithiole-4,5-dithionate(2-)] as an extended pi-electron system, [NBu4n](2) [Pt(C8H4S8)(2)] and Pt(Et2S)(2)(C8H4S8) were prepared. They were oxidized by the ferrocenium, the decamethylferrocenium cation or iodine to form [NBu4n](x)[Pt(C8H4S8)(2)] (x = 0.05-0.4) and Pt(C8H4S8) (Et2S)(0.3)I-1.8, which exhibited electrical conductivities of 1.1-6.9 S cm(-1), measured for compacted pellets at room temperature. The crystal structure of the pro-ligand compound, C8H4S8(CH2CH2CN)(2), revealed a one-dimensional array of dimerized molecules constructed with some sulfur-sulfur non-bonded contacts. (C) 1998 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00103-0
• 作为产物：
  描述：

  trans-dichlorobis(diethyl sulfide)platinum(II) 、 4,5-bis(p-acetoxybenzylsulfanyl)-4',5'-ethylenedisulfanyltetrathiafulvalene 在 Na 作用下， 以 甲醇 为溶剂， 以61%的产率得到Pt(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithiolate(2-))(diethylsulfide)2
  参考文献：
  名称：

  Preparation and properties of C8H4S8-platinum(II) complexes and electrical conductivities of their oxidized species and X-ray crystal structure of C8H4S8(CH2CH2CN)2 as a pro-ligand compound

  摘要：

  Using the C8H4S82- ligand [2-{(4,5-ethylenedithio)-1,3-dithiole-2-ylidiene}-1,3-dithiole-4,5-dithionate(2-)] as an extended pi-electron system, [NBu4n](2) [Pt(C8H4S8)(2)] and Pt(Et2S)(2)(C8H4S8) were prepared. They were oxidized by the ferrocenium, the decamethylferrocenium cation or iodine to form [NBu4n](x)[Pt(C8H4S8)(2)] (x = 0.05-0.4) and Pt(C8H4S8) (Et2S)(0.3)I-1.8, which exhibited electrical conductivities of 1.1-6.9 S cm(-1), measured for compacted pellets at room temperature. The crystal structure of the pro-ligand compound, C8H4S8(CH2CH2CN)(2), revealed a one-dimensional array of dimerized molecules constructed with some sulfur-sulfur non-bonded contacts. (C) 1998 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00103-0