| 1266239-86-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• CAS: 1266239-86-4
• 化学式: C₄₂H₆₈MgN₁₀Si₂
• 分子量: 793.545
• InChiKey: FETOYOXXPULOGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-吡啶甲酯 、 PhN(Na)SiMe3 在 magnesium dibromide bis(tetrahydrofuran) adduct 作用下， 以 乙醚 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Magnesium(II) Complexes of 2,4-N,N′-Disubstituted 1,3,5-Triazapentadienyl Ligands: Synthesis and Characterization of [N(Dipp)C(NMe₂)NC(NMe₂)N(SiMe₃)MgBr]₂ and [N(R)C(R′)NC(R′)N(SiMe₃)]₂Mg (Dipp = 2,6-ⁱPr₂−C₆H₃, R = Ph, SiMe₃; R′ = NMe₂, 1-piperidino)

  摘要：

  Treatment of the appropriate lithium or sodium 2,4-N,N'-disubstituted 1,3,5-triazapentadienate [RNC(R')NC(R')-N(SiMe3)M](2) (R = Ph, 2,6-Pr-i(2)-C6H3(Dipp) or SiMe3; R' = NMe2 or 1-piperidino; M = Li or Na) with one or half equivalent portion of MgBr2(THF)(2) in Et2O under mild conditions furnishes in good yield the first structurally characterized molecular magnesium 2,4-N,N'-disubstituted 1,3,5-triazapentadienates [DippNC(NMe2)NC(NMe2)N(SiMe3)MgBr](2) (1), [{RNC(R')NC(R')N(SiMe3)}(2)Mg] (R = Ph, R' = NMe2 2; R = Ph, R' = 1-piperidino 3; R = SiMe3, R' = 1-piperidino 4). The solid-state structure of 1 is dimeric and those of 2, 3, and 4 are monomeric. The ligand backbone NCNCN in 1 adopts a W-shaped configuration, while in 2, 3 and 4 adopts a U-shaped configuration.

  DOI：

  10.1021/ic102401w