[(oleylamine)AuCl] | 1040407-03-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: [(oleylamine)AuCl]
• CAS: 1040407-03-1
• 化学式: Au*C₁₈H₃₇N*Cl
• 分子量: 499.918
• InChiKey: ADJUKOFLSONQFU-XXAVUKJNSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.98
• 重原子数：
  21.0
• 可旋转键数：
  15.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  26.02
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  [(oleylamine)AuCl] 在 银 作用下， 以 正己烷 为溶剂， 生成 金
  参考文献：
  名称：

  Ultrathin Gold Nanowires Can Be Obtained by Reducing Polymeric Strands of Oleylamine−AuCl Complexes Formed via Aurophilic Interaction

  摘要：

  This communication describes a facile route to the preparation of ultrathin gold nanowires using linear chains formed from [{oleylamine)AuCl] complex via aurophilic interaction. The linear chains, with Au-I center dot center dot center dot Au-I bonds as the backbone and surrounded by oleylaimines, can group together to form bundles of polymeric strands. When the Au-I was reduced to Au-0 by reacting with Ag nanoparticles in hexane, the polymeric strands functioned as both the source of Au and the template to media the nucleation and growth of Au nanowires. Using this method, we were able to produce Au nanowires with an average diameter of similar to 1.8 nm and an aspect ratio of >1000 in high yields (similar to 70%).

  DOI：

  10.1021/ja803343m
• 作为产物：
  描述：

  油胺 、 gold(I) chloride 以 正己烷 为溶剂， 生成 [(oleylamine)AuCl]
  参考文献：
  名称：

  Ultrathin Gold Nanowires Can Be Obtained by Reducing Polymeric Strands of Oleylamine−AuCl Complexes Formed via Aurophilic Interaction

  摘要：

  This communication describes a facile route to the preparation of ultrathin gold nanowires using linear chains formed from [{oleylamine)AuCl] complex via aurophilic interaction. The linear chains, with Au-I center dot center dot center dot Au-I bonds as the backbone and surrounded by oleylaimines, can group together to form bundles of polymeric strands. When the Au-I was reduced to Au-0 by reacting with Ag nanoparticles in hexane, the polymeric strands functioned as both the source of Au and the template to media the nucleation and growth of Au nanowires. Using this method, we were able to produce Au nanowires with an average diameter of similar to 1.8 nm and an aspect ratio of >1000 in high yields (similar to 70%).

  DOI：

  10.1021/ja803343m