gold decanethiolate | 1054450-58-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: gold decanethiolate
• CAS: 1054450-58-6
• 化学式: Au*C₁₀H₂₁S
• 分子量: 370.309
• InChiKey: BCOHGAQSBKFBKK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.67
• 重原子数：
  12.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  gold decanethiolate 以 四氢呋喃 为溶剂， 生成 金
  参考文献：
  名称：

  Synthesis of Gold Nanoparticles from Gold(I)−Alkanethiolate Complexes with Supramolecular Structures through Electron Beam Irradiation in TEM

  摘要：

  Monodisperse gold nanoparticles were prepared via electron beam irradiation of Au(I)-SR (R = -CnH2n+1) polymers with highly ordered supramolecular structures in transmission electron microscopy. The Au(I)-SR polymers were synthesized simply by mixing LiAuCl4 and an excess amount of alkanethiol in tetrahydrofuran. The sizes of the gold nanoparticles were controlled by changing the length of the alkyl group or by adjusting the energy of the electron beam.

  DOI：

  10.1021/ja042423x
• 作为产物：
  描述：

  四氯金(III)酸锂水合物 、 1-癸硫醇 以 四氢呋喃 为溶剂， 生成 gold decanethiolate
  参考文献：
  名称：

  Synthesis of Gold Nanoparticles from Gold(I)−Alkanethiolate Complexes with Supramolecular Structures through Electron Beam Irradiation in TEM

  摘要：

  Monodisperse gold nanoparticles were prepared via electron beam irradiation of Au(I)-SR (R = -CnH2n+1) polymers with highly ordered supramolecular structures in transmission electron microscopy. The Au(I)-SR polymers were synthesized simply by mixing LiAuCl4 and an excess amount of alkanethiol in tetrahydrofuran. The sizes of the gold nanoparticles were controlled by changing the length of the alkyl group or by adjusting the energy of the electron beam.

  DOI：

  10.1021/ja042423x

文献信息

• A complex of gold(I) benzenethiolate with isocyanide: synthesis and crystal and molecular structures
  作者：V. P. Dyadchenko、N. M. Belov、M. A. Dyadchenko、Yu. L. Slovokhotov、A. M. Banaru、D. A. Lemenovskii

  DOI：10.1007/s11172-010-0143-y

  日期：2010.3

  Abstract2,6-Dimethylphenyl isocyanide forms complexes with gold( I) chloride (complex 4) and gold(I) benzenethiolate (complex 5) but forms no stable complexes with gold alkanethiolates. A reaction of complex 5 with tetramethylthiuram disulfide yields gold(I) dimethyldithiocar-bamate. Stable gold(III) derivatives cannot be obtained in such a way. Shortened intermolecular Au...Au contacts in complexes

  摘要 2,6-二甲基苯基异氰化物与氯化金（I）（络合物4）和苯硫醇金（络合物5）形成络合物，但与链烷硫醇金不形成稳定的络合物。络合物 5 与二硫化四甲基秋兰姆反应生成二甲基二硫代氨基甲酸金 (I)。以这种方式无法获得稳定的金 (III) 衍生物。复合物 4 和 5 中缩短的分子间 Au...Au 接触（X 射线衍射）表明它们中存在“亲金”相互作用。