2-[2-[2-(3-Trimethoxysilylpropylamino)ethylamino]ethyliminomethyl]phenol | 1373150-75-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2-[2-[2-(3-Trimethoxysilylpropylamino)ethylamino]ethyliminomethyl]phenol
• CAS: 1373150-75-4
• 化学式: C₁₇H₃₁N₃O₄Si
• 分子量: 369.536
• InChiKey: QJOLSBZEAZWMGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.26
• 重原子数：
  25
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  84.3
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2-[2-[2-(3-Trimethoxysilylpropylamino)ethylamino]ethyliminomethyl]phenol 、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  Design of a bio-inspired copper (II) Schiff base complex grafted in mesoporous silica for catalytic oxidation

  摘要：

  Controlled grafting of a copper (II) complex with a Schiff base ligand (L-A = N-(salicylaldimine)-(N'-propyltrimethoxysilane)-diethylenetriamine) on a mesoporous MCM-41 type of silica (LUS) was accomplished using a pattering technique to allow a homogeneous distribution of isolated copper sites on the solid using trimethylsilyl groups as dispersing function. XRD patterns suggest that the final material LUS-CuLA exhibits a well-ordered 2D hexagonal structure. Elemental analysis, solid UV-Vis and EPR spectroscopies indicate that the copper (II) coordination sphere is most likely of a 3N10 type with an additional acetate ion as a ligand. Almost all the Cu(II) species grafted on the solid were EPR active (2.6 wt% active species for 2.8 wt% total copper measured from ICP-MS analysis) confirming the presence of monomeric copper species. Preliminary catalytic tests for phenol hydroxylation show that the supported system presents similar activity as the molecular analogue. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.06.039
• 作为产物：
  描述：

  水杨醛 、 二乙烯三胺基丙基三甲氧基硅烷 以 乙醇 为溶剂， 反应 6.0h， 生成 2-[2-[2-(3-Trimethoxysilylpropylamino)ethylamino]ethyliminomethyl]phenol
  参考文献：
  名称：

  Design of a bio-inspired copper (II) Schiff base complex grafted in mesoporous silica for catalytic oxidation

  摘要：

  Controlled grafting of a copper (II) complex with a Schiff base ligand (L-A = N-(salicylaldimine)-(N'-propyltrimethoxysilane)-diethylenetriamine) on a mesoporous MCM-41 type of silica (LUS) was accomplished using a pattering technique to allow a homogeneous distribution of isolated copper sites on the solid using trimethylsilyl groups as dispersing function. XRD patterns suggest that the final material LUS-CuLA exhibits a well-ordered 2D hexagonal structure. Elemental analysis, solid UV-Vis and EPR spectroscopies indicate that the copper (II) coordination sphere is most likely of a 3N10 type with an additional acetate ion as a ligand. Almost all the Cu(II) species grafted on the solid were EPR active (2.6 wt% active species for 2.8 wt% total copper measured from ICP-MS analysis) confirming the presence of monomeric copper species. Preliminary catalytic tests for phenol hydroxylation show that the supported system presents similar activity as the molecular analogue. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.06.039