1,5-dioxa-9-aza-3-ethyl-3-hydroxymethyl-8,8,10,10-tetramethyl-9-undecyloxyspiro[5.5]undecane | 863636-63-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: 1,5-dioxa-9-aza-3-ethyl-3-hydroxymethyl-8,8,10,10-tetramethyl-9-undecyloxyspiro[5.5]undecane
• 英文别名: (3-Ethyl-8,8,10,10-tetramethyl-9-undecoxy-1,5-dioxa-9-azaspiro[5.5]undecan-3-yl)methanol
• CAS: 863636-63-9
• 化学式: C₂₆H₅₁NO₄
• 分子量: 441.695
• InChiKey: SCRBTDRWMKWENR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  31
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.2
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  碳酸二苯酯 、 1,5-dioxa-9-aza-3-ethyl-3-hydroxymethyl-8,8,10,10-tetramethyl-9-undecyloxyspiro[5.5]undecane 在 potassium carbonate 作用下， 以 mineral spirit 为溶剂， 反应 8.0h， 以39.5%的产率得到Bis[(3-ethyl-8,8,10,10-tetramethyl-9-undecoxy-1,5-dioxa-9-azaspiro[5.5]undecan-3-yl)methyl] carbonate
  参考文献：
  名称：

  WEAKLY BASIC HINDERED AMINES HAVING CARBONATE SKELETONS, SYNTHETIC RESIN COMPOSITIONS, AND COATING COMPOSITIONS

  摘要：

  公开号：

  EP1731508B1
• 作为产物：
  描述：

  1-undecanoxy-2,2,6,6-tetramethyl piperidine-4-one 、 三羟甲基丙烷 在 甲醇 、 对甲苯磺酸 作用下， 以 环己烷 为溶剂， 反应 9.0h， 以80.6%的产率得到1,5-dioxa-9-aza-3-ethyl-3-hydroxymethyl-8,8,10,10-tetramethyl-9-undecyloxyspiro[5.5]undecane
  参考文献：
  名称：

  WEAKLY BASIC HINDERED AMINES HAVING CARBONATE SKELETONS, SYNTHETIC RESIN COMPOSITIONS, AND COATING COMPOSITIONS

  摘要：

  公开号：

  EP1731508B1

文献信息

• Weakly Basic Hindered Amines Having Carbonate Skeletons, Synthetic Resin Compositions, And Coating Compositions
  申请人：Negishi Yoshinori

  公开号：US20090111699A1

  公开（公告）日：2009-04-30

  Hindered amines represented by the general formula (I): (wherein R is an alkyl or hydroxyalkyl group having 1 to 30 carbon atoms or alkenyl having 2 to 30 carbon atoms; n is an integer of 1 to 4; when n is 1, R 1 is alkyl having 1 to 22 carbon atoms, alkenyl having 2 to 22 carbon atoms, or a group represented by the general formula (III): (R is as defined above), while when n is 2 to 4, R 1 is an n-valent organic group having 2 to 20 carbon atoms). When added to synthetic resins or coating materials, the amines can impart long-period stabilizing effect to the resins or the materials and exhibit excellent resistance to extraction with acid rain or chemicals.
• Weakly Basic Hindered Amines Compounds Having Carbonate Skeletons, Synthetic Resin Compositions And Coating Compositions
  申请人：Negishi Yoshinori

  公开号：US20100190898A1

  公开（公告）日：2010-07-29

  Hindered amines represented by the general formula (I): (wherein R is an alkyl or hydroxyalkyl group having 1 to 30 carbon atoms or alkenyl having 2 to 30 carbon atoms; n is an integer of 1 to 4; when n is 1, R 1 is alkyl having 1 to 22 carbon atoms, alkenyl having 2 to 22 carbon atoms, or a group represented by the general formula (III): (R is as defined above), while when n is 2 to 4, R 1 is an n-valent organic group having 2 to 20 carbon atoms). When added to synthetic resins or coating materials, the amines can impart long-period stabilizing effect to the resins or the materials and exhibit excellent resistance to extraction with acid rain or chemicals.
• US8329787B2
  申请人：——

  公开号：US8329787B2

  公开（公告）日：2012-12-11
• US9133121B2
  申请人：——

  公开号：US9133121B2

  公开（公告）日：2015-09-15