[Mn(8-ethyl-5,8-dihydro-5-oxo-2-(1-piperazinyl)-pyrido(2,3-d)pyrimidine-6-carboxylate)2(H2O)] | 881212-38-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Mn(8-ethyl-5,8-dihydro-5-oxo-2-(1-piperazinyl)-pyrido(2,3-d)pyrimidine-6-carboxylate)2(H2O)]
• 英文别名: [Cu(pipemidic acid(-1H))2(H2O)]
• CAS: 881212-38-0
• 化学式: C₂₈H₃₄MnN₁₀O₇
• 分子量: 677.579
• InChiKey: BTIFCPRJQYBVCF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 吡哌酸 、 manganese(ll) chloride 在 Et₃N 作用下， 以 甲醇 为溶剂， 以80%的产率得到[Mn(8-ethyl-5,8-dihydro-5-oxo-2-(1-piperazinyl)-pyrido(2,3-d)pyrimidine-6-carboxylate)2(H2O)]
  参考文献：
  名称：

  Synthesis and spectroscopic study of copper(II) and manganese(II) complexes with pipemidic acid

  摘要：

  The interaction of copper(II) and manganese(II) with pipemidic acid, Hpipem, afforded the complexes [Cu(pipem)(2)(H2O)](.)2H(2)O, 1 and [Mn(pipem)(2)(H2O)], 2. The new complexes have been characterised by elemental analyses, infrared, UV-vis and X-band EPR spectroscopy in the temperature range from 4 to 300 K. The monoanion, pipem, exhibits O,O ligation through the carbonyl and carboxylato oxygen atoms. Five coordinate square-pyramid configuration has been proposed for 1 and 2, and the fifth apical position is occupied by a coordinated water molecule. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.05.038