作者:M. S. Grigor’ev、N. A. Budantseva、A. M. Fedoseev
DOI:10.1134/s1070328410020120
日期:2010.2
The single crystals of the Np(V) complex (NH4)[NpO2(CO3)] (I) were synthesized and studied by X-ray diffraction. At 100 K, the crystals are hexagonal, space group P63 μmc, a = 5.0734(1) Å, c = 10.9191(2) Å, V= 243.399(11) Å3, Z = 2, ρ(calcd) = 4.735 g/cm3. The absorption spectra of a crystal of I in the visible and infrared ranges were measured.
合成并通过X射线衍射研究了Np(V)配合物(NH 4)[NpO 2(CO 3)](I)的单晶。在100K,该晶体为六角形,空间群P 6 3 μmc,一个= 5.0734(1)埃,c ^ = 10.9191(2),V = 243.399(11)一种3,Ž = 2,ρ(计算值)= 4.735克/厘米3。测量了I晶体在可见光和红外范围内的吸收光谱。