1,1-bis(4-(aminophenoxy)phenyl)-1-(4-(4-amino-2-trifluoromethylphenoxy)phenyl)ethane | 1266615-35-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 1,1-bis(4-(aminophenoxy)phenyl)-1-(4-(4-amino-2-trifluoromethylphenoxy)phenyl)ethane
• CAS: 1266615-35-3
• 化学式: C₃₉H₃₂F₃N₃O₃
• 分子量: 647.697
• InChiKey: SQAAFGBILPJSHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.18
• 重原子数：
  48.0
• 可旋转键数：
  9.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  105.75
• 氢给体数：
  3.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  1,1-bis(4-(nitrophenoxy)phenyl)-1-(4-(4-nitro-2-trifluoromethylphenoxy)phenyl)ethane 在 palladium 10% on activated carbon 、 氢气 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 15.0h， 以92%的产率得到1,1-bis(4-(aminophenoxy)phenyl)-1-(4-(4-amino-2-trifluoromethylphenoxy)phenyl)ethane
  参考文献：
  名称：

  Preparation and properties of polyimide–silica hybrid films with conjugation of the polyimide and silica by a sol–gel process using 3-(triethoxysilyl)propyl succinic anhydride

  摘要：

  New polyimide-silica hybrid materials were prepared using the polyamic acid synthesized by copolymerization of 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA), 4,4'-oxydianiline (ODA) and an A(2)A'-type tri-functional amine, 1,1-bis(4-(aminophenoxy)phenyl)-1-(4-(4-amino-2-trifluoromethylphenoxy)phenyl)ethane (1) (BTDA:ODA:1 = 7:6:1 in the molar). 3-(Triethoxysilyl)propyl succinic anhydride(TESSA) was reacted with amino groups in polyamic acid to introduce ethoxysilyl moiety which act as conjugation site for silica. The polyimide-silica hybrid films were prepared by a sol-gel reaction of tetraethoxysilane (TEOS) in a solution of the polyamic acid, followed by thermal imidation. Self-standing films were obtained with up to 50 wt.% silica, and transparent films were obtained at up to 40 wt.% silica. Dynamic-mechanical and mechanical analyses were carried out to examine the properties of hybrid films. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2010.11.015