4-(4'-dodecyloxybenzoyloxy)-3-methoxy benzaldehyde | 314059-00-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-(4'-dodecyloxybenzoyloxy)-3-methoxy benzaldehyde
• 英文别名: 4-(4-(n-dodecyloxy)benzoyloxy)-3-methoxybenzaldehyde；(4-formyl-2-methoxyphenyl) 4-dodecoxybenzoate
• CAS: 314059-00-2
• 化学式: C₂₇H₃₆O₅
• 分子量: 440.58
• InChiKey: RLBCUKZKOFQQMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.03
• 重原子数：
  32.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  61.83
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  4-(4'-dodecyloxybenzoyloxy)-3-methoxy benzaldehyde 在 Jones reagent 作用下， 以 丙酮 为溶剂， 以30%的产率得到4-(4-(n-dodecyloxy)benzoyloxy)-3-methoxybenzoic acid
  参考文献：
  名称：

  Synthesis of banana-like 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene esters and luminescence of their terbium(III) complexes

  摘要：

  New esters of 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene with 4-(4-alkoxybenzoyloxy)-2-(or 3-)methoxybenzoic acids were synthesized. The correlation between their structure and liquid crystal properties was examined, and the luminescence characteristics of terbium(III) complexes with these esters were studied.

  DOI：

  10.1134/s1070427211060139
• 作为产物：
  描述：

  4-十二烷氧基苯甲酸 在 吡啶 、 氯化亚砜 作用下， 生成 4-(4'-dodecyloxybenzoyloxy)-3-methoxy benzaldehyde
  参考文献：
  名称：

  Synthesis of a New Mesogenic Homologous Series Containing Naphthalene Moiety

  摘要：

  A new series of mesogenic Schiffs base esters, 4-(4'-n-Alkoxyhenzoyloxy) 3-methoxy benzylidene 2 "-aminonaphthalenes has been synthesized. The synthesized compounds were characterised by elemental analysis and standard spectroscopic methods.All the homologues synthesized exhibit mesomorphism. The mesomorphic properties of the present series are compared with other structurally related series.Chiral nematic mesophase (N*) is induced in the system by doping a derivative of naturally occurring chiral compound.

  DOI：

  10.1080/10587250008024796

文献信息

• Effect of Lateral Substitution on Mesomorphism: (A) 4(4'-<i>n</i>-Alkoxybenzoyloxy)-3-methoxy benzaldehydes (B) 4(4'-<i>n</i>-Alkoxybenzoyloxy)-3-methoxy benzylidene-4”-toluidines (C) 4(4'-<i>n</i>-Alkoxybenzoyloxy)-3-methoxy benzylidene-4”-anisidines
  作者：R. A. Vora、Renu Gupta

  DOI：10.1080/00268948208071025

  日期：1982.2