trimethyl-[(4E)-4-(trimethylsilylmethylidene)dec-1-ynyl]silane | 834897-81-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: trimethyl-[(4E)-4-(trimethylsilylmethylidene)dec-1-ynyl]silane
• CAS: 834897-81-3
• 化学式: C₁₇H₃₄Si₂
• 分子量: 294.628
• InChiKey: AKKHPIOVRWRUGZ-WUKNDPDISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.03
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trimethyl-[(4E)-4-(trimethylsilylmethylidene)dec-1-ynyl]silane 在 四丁基氟化铵 作用下， 以72%的产率得到
  参考文献：
  名称：

  A novel propargyltitanation of acetylenes. Heteroatom substituent-dependent manifold in intermolecular coupling of allene and acetylene

  摘要：

  Titanium alkoxide-mediated coupling of functionalized allenes and acetylenes afforded various types of producuts, and the first propargyltitanation of acetylenes was achieved by the appropriate choice of allenes. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.049
• 作为产物：
  描述：

  trimethyl(oct-1-yn-1-yl)silane 、 1-(Phenylthio)-1-(trimethylsilyl)-1,2-propadiene 在 titanium(IV) isopropylate 、 异丙基氯化镁 、 氢气 作用下， 以67%的产率得到trimethyl-[(4E)-4-(trimethylsilylmethylidene)dec-1-ynyl]silane
  参考文献：
  名称：

  A novel propargyltitanation of acetylenes. Heteroatom substituent-dependent manifold in intermolecular coupling of allene and acetylene

  摘要：

  Titanium alkoxide-mediated coupling of functionalized allenes and acetylenes afforded various types of producuts, and the first propargyltitanation of acetylenes was achieved by the appropriate choice of allenes. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.049

文献信息

• A novel propargyltitanation of acetylenes. Heteroatom substituent-dependent manifold in intermolecular coupling of allene and acetylene
  作者：Ryoichi Tanaka、Misa Sasaki、Fumie Sato、Hirokazu Urabe

  DOI：10.1016/j.tetlet.2004.11.049

  日期：2005.1

  Titanium alkoxide-mediated coupling of functionalized allenes and acetylenes afforded various types of producuts, and the first propargyltitanation of acetylenes was achieved by the appropriate choice of allenes. (C) 2004 Elsevier Ltd. All rights reserved.