O,O-dibutyldithiophosphoric acid | 2253-44-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: O,O-dibutyldithiophosphoric acid
• 英文别名: dibutyl dithiophosphoric acid；dibutyl dithiophosphate；Dithiophosphorsaeure-O,O'-dibutylester；O.O-Dibutyl-dithiophosphat；Dibutyldithiophosphat；Dibutyldithiophosphorsaeure；dibutoxy-sulfanyl-sulfanylidene-λ5-phosphane
• CAS: 2253-44-3
• 化学式: C₈H₁₉O₂PS₂
• 分子量: 242.343
• InChiKey: XPRULOZMJZDZEF-UHFFFAOYSA-N

物化性质

• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.6
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  O,O-dibutyldithiophosphoric acid 在 氢氧化钾 、 碘 作用下， 生成 Bis--disulfid
  参考文献：
  名称：

  Sanin; Scher, 1957, vol. 2, # 3, p. 38,41

  摘要：

  DOI：
• 作为产物：
  描述：

  dibutyldithiophosphate ammonium 在 硫酸 作用下， 以 水 为溶剂， 以98%的产率得到O,O-dibutyldithiophosphoric acid
  参考文献：
  名称：

  Characterization of Dialkyldithiophosphates as Slow Hydrogen Sulfide Releasing Chemicals and Their Effect on the Growth of Maize

  摘要：

  Hydrogen sulfide is a key gasotransmitter for plants and has been shown to greatly increase their growth and survival in the presence of environmental stressors. Current methods for slowly releasing hydrogen sulfide use chemicals, such as GYY-4137, but these result in the release of chemicals not found in the environment, and chemicals used may lack structures that can be readily tuned to affect the rate of release of hydrogen sulfide. In this article, we describe the synthesis and slow release of hydrogen sulfide from dialkyldithiophosphates, which are a new set of hydrogen sulfide releasing chemicals that can be used in agriculture. The rates of hydrolysis of dibutyldithiophosphate and GYY-4137 were measured in water at 85 degrees C and compared with each other to investigate their differences. GYY-4137 is widely used as a chemical that slowly releases H2S, but its rate of release was not previously quantified. The release of hydrogen sulfide in water at room temperature was measured for a series of dialkyldithiophosphates using a hydrogen sulfide electrode. It was shown that the structure of the dialkyldithiophosphate affected the amount of hydrogen sulfide released. The final degradation products of dibutyldithiophosphate were shown to be phosphoric acid and butanol, which are chemicals found in the environment. This result was notable because it demonstrated that dialkyldithiophosphates degrade to safe, natural chemicals that will not pollute the environment. To demonstrate that dialkyldithiophosphates have potential applications in agriculture, maize was grown for 4.5 weeks after exposure to 1-200 mg of dibutyldithiophosphate, and the weight of corn plants increased by up to 39% at low loadings of dibutyldithiophosphate.

  DOI：

  10.1021/acs.jafc.9b04398
• 作为试剂：
  描述：

  2-氯-5-异氰酸硝基苯 在 O,O-dibutyldithiophosphoric acid 、 乙醇 作用下， 以 苯 为溶剂， 反应 4.0h， 生成 butyl hydrogen (N,N'-diphenylamidino)phosphonate inner salt
  参考文献：
  名称：

  Kamalov, R. M.; Makarov, G. M.; Islamov, R. G., Journal of general chemistry of the USSR, 1990, vol. 60, # 4.1, p. 680 - 686

  摘要：

  DOI：

文献信息

• Synthesis and characterization of pyridoxine, nicotine and nicotinamide salts of dithiophosphoric acids as antibacterial agents against resistant wound infection
  作者：Trinh Dang、Ilyas S. Nizamov、Ramazan Z. Salikhov、Leysan R. Sabirzyanova、Vyacheslav V. Vorobev、Tatyana I. Burganova、Marina M. Shaidoullina、Elvira S. Batyeva、Rafael A. Cherkasov、Timur I. Abdullin

  DOI：10.1016/j.bmc.2018.11.017

  日期：2019.1

  The pyridine-derived biomolecules are of considerable interest in developing medicinal compounds with various specific activities. Novel ammonium salts of pyridoxine, (S)-(–)-nicotine and nicotinamide with O,O-diorganyl dithiophosphoric acids (DTPA) were synthesized and characterized. The complexation of chiral monoterpenyl DTPA, including (S)-(–)-menthyl, (R)-(+)-menthyl, (1R)-endo-(+)-fenchyl, (1S

  吡啶衍生的生物分子在开发具有各种特定活性的药用化合物方面引起了极大的兴趣。合成并表征了吡ido醇，（S）-（-）-烟碱和烟酰胺与O，O-二有机基二硫代磷酸（DTPA）的新型铵盐。手性单萜烯基DTPA的络合物，包括（S）-（–）-薄荷基，（R）-（+）-薄荷基，（1 R）-内-（+）-芬基，（1 S，2 S，3 S，5 R）-（+）-异樟脑油酰基衍生物与吡ido醇和尼古丁一起提供了有效的抗菌化合物3a，b，e，f和5a，b，d，f革兰氏阳性菌的MIC值低至10 µM（6 µg / mL）。两种基于薄荷基DTPA 3a和5a的吡pyr醇和尼古丁盐具有类似的活性，可抵抗包括MRSA在内的烧伤创面产生的抗药性细菌。这些化合物具有增强的两亲性和溶血性，并有效改变了铜绿假单胞菌和金黄色葡萄球菌的表面特性和基质分泌能力。3a和5a的MBC / MIC比表明其作用的杀菌模式。此外，这些化合物对人皮肤成纤维细胞具有中等的细胞毒性（IC
• A31 P NMR study ofO,O′-dialkyldithiophosphates: An unusual coupling
  作者：G. Joseph Ray、Gunter Caspari

  DOI：10.1002/mrc.1260251102

  日期：1987.11

  A series of O,O′-dialkyldithiophosphoric acids have been studied by 31P NMR, and a four-bond 31P-1H scalar coupling has been detected. This coupling is unusual because it is observed between phosphorus and only one of two available protons located on the same carbon, even when the alkyl fragment is simply an alkane that should not show any conformational preference. Variation of the structural features of the alkyl group showed that this coupling involved a “W” pathway.

  一系列O,O′-二烷基二硫代磷酸已通过31P NMR进行了研究，并检测到一个四键31P-1H标量耦合。这种耦合是异常的，因为它仅在磷和位于同一碳上的两个可用质子中的一个之间观察到，即便当烷基片段只是简单的烷烃时，不应表现出任何构象偏好。烷基基团结构特征的变化表明，这种耦合涉及一个“W”路径。
• 디알킬 디티오포스페이트 그룹을 포함하는 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활제 조성물
  申请人：KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY 한국화학연구원(319980077651)

  公开号：KR20170113745A

  公开（公告）日：2017-10-13

  본 발명은 디알킬 디티오포스페이트 그룹을 포함하는 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활제 조성물에 관한 것이다. 본 발명에 따른 디알킬 디티오포스페이트 그룹을 포함하는 디카르복실산 유도체 화합물을 포함하는 윤활유 조성물은 내마모성능이 종래 윤활유 조성물보다 우수할 뿐만 아니라, 종래 윤활유 조성물보다 적은 함량으로 사용하여도 보다 우수한 효과를 나타내고, 중금속을 사용하지 않아 친환경적이므로, 엔진유, 변속기용 윤활유, 기어-기름, 터빈유, 작동유, 냉동기유, 압축기유, 진공펌프유, 베어링유, 미끄럼면유, 작암유, 금속 절삭유, 소성가공유, 열처리유, 윤활유 또는 가공유의 첨가제로 유용하게 사용될 수 있다.

  该专利涉及包含二烷基二硫代磷酸酯基团的二羧酸衍生物以及包含该衍生物的抗磨剂和润滑剂配方。根据本发明，含有二烷基二硫代磷酸酯基团的二羧酸衍生物化合物的润滑油配方不仅具有比传统润滑油配方更优越的抗磨性能，而且即使使用较少的量也能表现出更卓越的效果，并且由于不使用重金属，因此环保性更好，可广泛用作发动机油、变速箱润滑油、齿轮油、涡轮油、作动油、冷冻机油、压缩机油、真空泵油、轴承油、滑动面油、切削油、热处理油、润滑油或加工油的添加剂。
• 중금속이 함유되지 않은 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활제 조성물
  申请人：KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY 한국화학연구원(319980077651)

  公开号：KR101785337B1

  公开（公告）日：2017-10-18

  본 발명은 중금속이 함유되지 않은 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활제 조성물에 관한 것이다. 본 발명에 따른 디카르복실산 유도체 화합물을 포함하는 윤활유 조성물은 내마모성능이 종래 윤활유 조성물보다 우수할 뿐만 아니라, 종래 윤활유 조성물보다 적은 함량으로 사용하여도 보다 우수한 효과를 나타내고, 중금속을 사용하지 않아 친환경적이므로, 엔진유, 변속기용 윤활유, 기어-기름, 터빈유, 작동유, 냉동기유, 압축기유, 진공펌프유, 베어링유, 미끄럼면유, 작암유, 금속 절삭유, 소성가공유, 열처리유, 윤활유 또는 가공유의 첨가제로 유용하게 사용될 수 있다.

  本发明涉及不含重金属的二羧酸衍生物及其所含的抗磨损和润滑剂组合物。包含根据本发明的二羧酸衍生物化合物的润滑油组合物不仅具有比传统润滑油组合物更优越的抗磨损性能，而且即使使用较少量也表现出更优越的效果，并且由于不含重金属而环保，可用作发动机油、变速器润滑油、齿轮油、涡轮油、作动油、冷冻机油、压缩机油、真空泵油、轴承油、滑动面油、切削油、热处理油、润滑油或加工油的添加剂，具有实用价值。
• 一种硫代磷酸酯的含钼噻二唑衍生物及其制备方法和应用
  申请人：洛阳太平洋联合石油化工有限公司

  公开号：CN111909211B

  公开（公告）日：2023-08-22

  本发明提供了一种硫代磷酸酯的含钼噻二唑衍生物，属于润滑油添加剂技术领域。所述硫代磷酸酯的含钼噻二唑衍生物的结构式为：其中R1和R2为C4‑C13的直链或带支链的烷基。本发明还提供了该硫代磷酸酯的含钼噻二唑衍生物的制备方法。该硫代磷酸酯的含钼噻二唑衍生物作为润滑油添加剂，具有良好的润滑性和高极压性能，热稳定性良好，是一种优异的润滑油减摩添加剂。