Thermosensitive copolymers, and forward osmosis water treatment devices and methods of using the same
申请人:Samsung Electronics Co., Ltd
公开号:EP2641927A1
公开(公告)日:2013-09-25
Disclosed is a thermosensitive copolymer, which includes a first repeating unit having a temperature-sensitive oligomer grafted thereto and a second repeating unit having an ionic moiety and a counter ion to the ionic moiety, wherein the temperature-sensitive oligomer is an oligomer including a repeating unit derived from a unsaturated monomer with a moiety represented by Chemical Formula 1 or Chemical Formula 2, or an oligomer including a repeating unit derived from a heterocyclic compound having C, N, and O and having a C=N bond in its ring.
[Chemical Formula 1] *-C(=O)N(R2)(R3)
In Chemical Formula 1,
R2 and R3 are each independently hydrogen or a linear or branched C1 to C6 alkyl group, a C3 to C7 cycloalkyl group, or a C6 to C10 aryl group, R2 and R3 are not both be hydrogen, and R2 and R3 may be combined to form a nitrogen containing heterocycle.
In Chemical Formula 2, R4 is a C2 to C5 alkylene group.
本发明公开了一种热敏共聚物,它包括具有接枝到其上的热敏低聚物的第一重复单元和具有离子基团及离子基团的反离子的第二重复单元,其中热敏低聚物是一种低聚物,包括从具有化学式 1 或化学式 2 所代表的基团的不饱和单体衍生的重复单元,或包括从具有 C、N 和 O 且在其环中具有 C=N 键的杂环化合物衍生的重复单元的低聚物。
[化学式 1] *-C(=O)N(R2)(R3)
在化学式 1 中
R2 和 R3 各自独立地为氢或直链或支链 C1 至 C6 烷基、C3 至 C7 环烷基或 C6 至 C10 芳基,R2 和 R3 不能都是氢,R2 和 R3 可结合形成含氮杂环。
在化学式 2 中,R4 是 C2 至 C5 亚烷基。