Reactivity of transition metal fluorides—X. Oxidation-reduction reactions of rhenium, osmium and iridium hexafluorides
作者:R.C. Burns、T.A. O'Donnell
DOI:10.1016/0022-1902(80)80287-9
日期:1980.1
Oxidation-reduction reactions of the hexafluorides of the third row transitionmetals rhenium, osmium and iridium with a selected series of reductants have been studied. The results have shown that oxidant strength increases progressively from rhenium hexafluoride to iridium hexafluoride. The results of this study have also been correlated with those of previous investigations in this series, and with
研究了第三排过渡金属rh,和铱的六氟化物与一系列选定的还原剂的氧化还原反应。结果表明,氧化剂的强度从六氟化rh到六氟化铱逐渐增加。这项研究的结果也与该系列以前的研究以及第三排过渡金属六氟化物的其他研究相关。已经发现了OsF 5,IrF 5,IrF 4和六氟金属盐(V)盐的新制备路线,以及Os(IV)的三氟膦配合物Os(PF 3)2 F 4的制备。