triethyl(ethylthio)silane | 18236-32-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: triethyl(ethylthio)silane
• 英文别名: ethanesulfenyl-triethyl-silane；Aethansulfenyl-triaethyl-silan；Triaethyl(aethylthio)silan；Triethyl-(ethylthio)-silan；Thioethoxy-triethylsilan；triethyl(ethylsulfanyl)silane
• CAS: 18236-32-3
• 化学式: C₈H₂₀SSi
• 分子量: 176.398
• InChiKey: GKERZYPJJMYYAR-UHFFFAOYSA-N

物化性质

• 沸点：
  56-58 °C
• 密度：
  0.8456 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.74
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三乙基硅烷 、 二乙烯基硫醚 在 dihydrogen hexachloroplatinate 作用下， 生成 triethyl(ethylthio)silane
  参考文献：
  名称：

  Voronkov,M.G. et al., Collection of Czechoslovak Chemical Communications, 1979, vol. 44, p. 742 - 749

  摘要：

  DOI：

文献信息

• The catalytic reactions of triethyl- and triethoxy-silane with unsaturated sulphides
  作者：M.G. Voronkov、N.N. Vlasova、S.A. Bolshakova、S.V. Kirpichenko

  DOI：10.1016/s0022-328x(00)90626-0

  日期：1980.5

  di-alkenyl sulphides of the type RS(CH2)nCHCH2 (R = C2H5, CH2CH, CH2CHCH2, C3H7, n = 0, 1 and 4) by triethyl- and triethoxy-silane, catalyzed by H2PtCl6·6 H2O, (Ph3P)3RhCl and (PhCN)2PdCl2·Ph3P, has been studied. The addition of hydrosilane to the double bond of alkenyl sulphide leads to a mixture of two isomeric monoadducts. The hydrosilane can cleave the CS bond of the initial sulphides giving the

  该类型的RS的单-和二-烯基硫化物的氢化硅烷化（CH 2）Ñ CHCH 2（R = C 2 H ^ 5，CH 2 CH，CH 2 CHCH 2，C 3 ħ 7，Ñ = 0 H 1 PtCl 6 ·6 H 2 O，（Ph 3 P）3 RhCl和（PhCN）2 PdCl 2 ·Ph 3催化三乙基-和三乙氧基-硅烷（1和4）P，已被研究。在链烯基硫的双键上加氢硅烷会导致两种异构单加合物的混合物。氢硅烷可以切割初始硫化物给予thiosilanes的相应衍生物的CS键，X 3 SIS（CH 2）Ñ CHCH 2（X = C 2 H ^ 5，C 2 H ^ 5 O）。烯基硫的氢化硅烷化伴随着一些副反应，例如脱氢缩合，还原和聚合。研究了催化剂性质，氢化硅烷和链烯基硫化物的结构对反应路线的影响。
• Ru‐catalyzed Formation of Thiosilanes and Selenosilanes using Dichalcogenides as a User‐Friendly Alternative to Thiols and Selenols
  作者：Krzysztof Kuciński、Marcin Gruszczyński、Grzegorz Hreczycho

  DOI：10.1002/cctc.202200961

  日期：2022.10.10

  The silylation/germylation of several disulfides/diselenides has been established by using commercially available ruthenium catalyst. As a result, several silylthioethers and their germanium and selenium analogs have been synthesized. Notably, the obtained thiosilanes were subsequently utilized in nucleophilic aromatic substitution reaction, leading to unsymmetrical sulfides.

  通过使用市售的钌催化剂已经建立了几种二硫化物/二硒化物的甲硅烷基化/胚芽化。结果，合成了几种甲硅烷基硫醚及其锗和硒类似物。值得注意的是，得到的硫硅烷随后被用于亲核芳族取代反应，导致硫化物不对称。
• A novel route to silylthioethers
  作者：Iwao Ojima、Mitsuru Nihonyanagi、Yoichiro Nagai

  DOI：10.1016/s0022-328x(00)95067-8

  日期：1973.3
• Kirilyuk, B. A.; Mel'nitskii, I. A.; Golub, N. M., Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, # 9, p. 1754 - 1758
  作者：Kirilyuk, B. A.、Mel'nitskii, I. A.、Golub, N. M.、Kiladze, T. K.、Kantor, E. A.、Rakhmankulov, D. L.

  DOI：——

  日期：——
• Dehydrogenative Coupling of Thiol with Hydrosilane Catalyzed by an Iron Complex
  作者：Kozo Fukumoto、Michiho Kasa、Tsukuru, Oya、Masumi Itazaki、Hiroshi Nakazawa

  DOI：10.1021/om200377e

  日期：2011.7.11

  Thermal reaction of RSH with Et(3)SiH in the presence of a catalytic amount of CpFe(CO)(2)Me exhibited dehydrogenative S-Si coupling to give RSSiEt(3). A plausible reaction mechanism is proposed involving an Fe(IV) complex with SR, SiEt(3), and H ligands, from which reductive elimination of SR and SiEt3 takes place to give RSSiEt(3).