(HO)6- | 133495-04-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: (HO)6-
• 英文别名: 4-[5-[4-[1,1-Bis[4-[4,4-bis(4-hydroxyphenyl)pentoxy]phenyl]ethyl]phenoxy]-2-(4-hydroxyphenyl)pentan-2-yl]phenol；4-[5-[4-[1,1-bis[4-[4,4-bis(4-hydroxyphenyl)pentoxy]phenyl]ethyl]phenoxy]-2-(4-hydroxyphenyl)pentan-2-yl]phenol
• CAS: 133495-04-2
• 化学式: C₇₁H₇₂O₉
• 分子量: 1069.35
• InChiKey: RLJNMKJXGISMQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.6
• 重原子数：
  80
• 可旋转键数：
  24
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  149
• 氢给体数：
  6
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  3- 在 palladium on activated charcoal 作用下， 以 四氢呋喃 、 环己烷 为溶剂， 反应 108.0h， 以66%的产率得到(HO)6-
  参考文献：
  名称：

  Hyperbranched macromolecules via a novel double-stage convergent growth approach

  摘要：

  A novel double-stage convergent growth approach for the preparation of dendritic macromolecules is described. In the first stage, convergent growth with 4,4-bis(4'-hydroxyphenyl)pentanol as the building block is used to create symmetrical dendritic structures containing a large number of phenolic ''surface'' functionalities. In the second stage of growth, these polyphenolic dendritic macromolecules are utilized as cores for the attachment of other dendritic macromolecules, derived from 3,5-dihydroxybenzyl alcohol, that contain a single benzylic bromide reactive group at their focal point. This two-stage process affords hyperbranched spherical macromolecules consisting of a flexible inner core surrounded by a more rigid outer layer. The double-stage convergent growth approach allows for the preparation of larger dendrimers in less time and with greater ease than the single-stage approach while retaining the advantages of near monodispersity and ease of purification and characterization.

  DOI：

  10.1021/ja00011a031

文献信息

• TEMPLATED SEMICONDUCTOR PARTICLES AND METHODS OF MAKING
  申请人：3M Innovative Properties Company

  公开号：EP1877468B1

  公开（公告）日：2012-01-18
• TEMPLATED METAL PARTICLES AND METHODS OF MAKING
  申请人：3M Innovative Properties Company

  公开号：EP1904558A2

  公开（公告）日：2008-04-02
• TEMPLATED METAL OXIDE PARTICLES AND METHODS OF MAKING
  申请人：Wendland Michael S.

  公开号：US20100234213A1

  公开（公告）日：2010-09-16

  Composite particles of a metal oxide particle within a crosslinked, cored dendrimer are described. Additionally, methods of making the composite particles and compositions that contain the composite particles are described.
• US7413607B2
  申请人：——

  公开号：US7413607B2

  公开（公告）日：2008-08-19
• US7956001B2
  申请人：——

  公开号：US7956001B2

  公开（公告）日：2011-06-07