1,3-diisopropoxy-1,3-dimethyl-1,3-disilacyclobutane | 198066-66-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,3-diisopropoxy-1,3-dimethyl-1,3-disilacyclobutane
• 英文别名: 1,3-Diisopropoxy-1,3-dimethyl-1,3-disilacyclobutane；1,3-dimethyl-1,3-di(propan-2-yloxy)-1,3-disiletane
• CAS: 198066-66-9
• 化学式: C₁₀H₂₄O₂Si₂
• 分子量: 232.47
• InChiKey: BBEWCCLSXIJGRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.08
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-diisopropoxy-1,3-dimethyl-1,3-disilacyclobutane 在 三氯化铁 、 乙酰氯 作用下， 生成 1,3-dichloro-1,3-dimethyl-1,3-disilacyclobutane
  参考文献：
  名称：

  Cross-Linkable Carbosilane Polymers with Imbedded Disilacyclobutane Rings Derived by Acyclic Diene Metathesis Polymerization

  摘要：

  Cyclolinear carbosilane polymers with disilacyclobutane (DSCB) rings in the main-chain structure were prepared by means of acyclic diene metathesis (ADMET) polymerization of the corresponding 1,3-dibutenyl-1,3-disilacyclobutanes. The copolymerization of a monomer of this type with a noncyclic organosilane diene allowed for the incorporation of a varying number of DSCB rings into the polymer backbone. Subsequent hydrogenation of the double bonds with p-toluenesulfonhydrazide resulted in a saturated hydrocarbon structure in the main chain without affecting the DSCB ring. All of the resultant polymers are well-defined materials with DSCB rings incorporated into the backbone structure, as evidenced by NMR spectroscopy and GPC analyses. The thermal behavior of these polymers was characterized by DSC and TGA. DSC indicated low T(g)s, and TGA evidenced high thermal stability in an inert atmosphere. In addition, large exothermic peaks were observed in the DSC, which indicated, along with the IR and solid-state Si-29 NMR spectra, that cross-linking occurs during heating to ca. 250 degreesC via opening of the imbedded DSCB rings. The swelling properties of the resultant, thermally stable, carbosilane network materials on exposure to various solvents were also examined.

  DOI：

  10.1021/ma049760a
• 作为产物：
  描述：

  methyl(chloromethyl)isopropoxychlorosilane 在 碘 、 magnesium 作用下， 以 四氢呋喃 、 1,2-二溴乙烷 为溶剂， 反应 5.5h， 以51.2%的产率得到1,3-diisopropoxy-1,3-dimethyl-1,3-disilacyclobutane
  参考文献：
  名称：

  苯并环丁烯聚碳硅烷聚合单体或树脂及其制 备方法

  摘要：

  本发明公开了式(Ⅰ)所示的1,3‑二甲基‑1,3‑二苯并环丁烯基二硅杂环丁烷及其制备方法，其特征是：苯并环丁烯聚碳硅烷聚合单体的制备方法是：在氮气保护下将异丙醇滴加入氯甲基甲基二氯硅烷中反应后减压蒸馏，得到氯甲基甲基异丙氧基氯硅烷；再制备1,3‑二异丙氧基‑1,3‑二甲基‑1,3‑二硅杂环丁烷；再与4‑溴苯并环丁烯的格氏试剂等搅拌反应后分离提纯即制得；进一步可制备聚碳硅烷均聚物、以及聚碳硅烷线性共聚物。采用本发明制备的苯并环丁烯聚碳硅烷树脂具有良好的热稳定性、化学稳定性、力学性能和电学性能，适用于微电子工业、航空航天、国防等领域。

  公开号：

  CN106866719B

文献信息

• Synthesis and characterization of cyano-substituted disilacyclobutane rings and poly(silylenemethylene) polymers
  作者：M Lienhard、C Wiegand、T Apple、L.V Interrante

  DOI：10.1016/s0022-328x(03)00510-2

  日期：2003.11

  The synthesis, and characterization by nuclear magnetic resonance (NMR) spectroscopy, of two cyano-substituted 1,3-disilacyclobutanes, 1,3-dicyano-1,3-dimethyl-1,3-disilacyclobutane, [Si(CN)(Me)CH2]2, and 1,1,3,3-tetracyano-1,3-disilacyclobutane, [Si(CN)2CH2]2, are reported. Evidence for a trans/cis exchange process in solution was obtained in the case of [Si(CN)(Me)CH2]2, where the initially obtained

  两种氰基取代的1,3-二硅环丁烷，1,3-二氰基-1,3-二甲基-1,3-二硅环丁烷[[Si（CN）（Me报道了）CH 2 ] 2和1,1,3,3-四氰基-1,3-二硅环丁烷[Si（CN）2 CH 2 ] 2。在[Si（CN）（Me）CH 2 ] 2的情况下，获得了溶液中反式/顺式交换过程的证据，其中通过NMR光谱观察到最初获得的全反式异构体，将其重新排列为在顺式和反式异构体。相应的聚（silylenemethylene）（PSM）聚合物，[硅（CN）（Me）的CH 2 ] Ñ和[硅（CN）2 CH 2 ] Ñ，通过交换装置在分别的完全和部分取代的形式获得反应在相应的氯代-PSMs上与三甲基甲硅烷基氰化物进行反应。发现作为聚（甲基丙烯腈）的硅类似物的[Si（CN）（Me）CH 2 ] n聚合物在33℃下显示出玻璃化转变。
• 苯并环丁烯聚碳硅烷聚合单体或树脂及其制 备方法
  申请人：西南科技大学

  公开号：CN106866719B

  公开（公告）日：2020-05-15

  本发明公开了式(Ⅰ)所示的1,3‑二甲基‑1,3‑二苯并环丁烯基二硅杂环丁烷及其制备方法，其特征是：苯并环丁烯聚碳硅烷聚合单体的制备方法是：在氮气保护下将异丙醇滴加入氯甲基甲基二氯硅烷中反应后减压蒸馏，得到氯甲基甲基异丙氧基氯硅烷；再制备1,3‑二异丙氧基‑1,3‑二甲基‑1,3‑二硅杂环丁烷；再与4‑溴苯并环丁烯的格氏试剂等搅拌反应后分离提纯即制得；进一步可制备聚碳硅烷均聚物、以及聚碳硅烷线性共聚物。采用本发明制备的苯并环丁烯聚碳硅烷树脂具有良好的热稳定性、化学稳定性、力学性能和电学性能，适用于微电子工业、航空航天、国防等领域。
• Cross-Linkable Carbosilane Polymers with Imbedded Disilacyclobutane Rings Derived by Acyclic Diene Metathesis Polymerization
  作者：Zhizhong Wu、Jerry P. Papandrea、Tom Apple、Leonard V. Interrante

  DOI：10.1021/ma049760a

  日期：2004.7.1

  Cyclolinear carbosilane polymers with disilacyclobutane (DSCB) rings in the main-chain structure were prepared by means of acyclic diene metathesis (ADMET) polymerization of the corresponding 1,3-dibutenyl-1,3-disilacyclobutanes. The copolymerization of a monomer of this type with a noncyclic organosilane diene allowed for the incorporation of a varying number of DSCB rings into the polymer backbone. Subsequent hydrogenation of the double bonds with p-toluenesulfonhydrazide resulted in a saturated hydrocarbon structure in the main chain without affecting the DSCB ring. All of the resultant polymers are well-defined materials with DSCB rings incorporated into the backbone structure, as evidenced by NMR spectroscopy and GPC analyses. The thermal behavior of these polymers was characterized by DSC and TGA. DSC indicated low T(g)s, and TGA evidenced high thermal stability in an inert atmosphere. In addition, large exothermic peaks were observed in the DSC, which indicated, along with the IR and solid-state Si-29 NMR spectra, that cross-linking occurs during heating to ca. 250 degreesC via opening of the imbedded DSCB rings. The swelling properties of the resultant, thermally stable, carbosilane network materials on exposure to various solvents were also examined.