pentachloro-1,1,1-trimethyltrisiloxane | 115147-32-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: pentachloro-1,1,1-trimethyltrisiloxane
• 英文别名: 1,1,1-trimethyl-3,3,5,5,5-pentachlorotrisiloxane；1,1,1,3,3-Pentachloro-5,5,5-trimethyltrisiloxane；trichloro-[dichloro(trimethylsilyloxy)silyl]oxysilane
• CAS: 115147-32-5
• 化学式: C₃H₉Cl₅O₂Si₃
• 分子量: 338.625
• InChiKey: DSJLIGBEGORVEA-UHFFFAOYSA-N

物化性质

• 沸点：
  215.4±23.0 °C(Predicted)
• 密度：
  1.328±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.92
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,1,1-三氯-3,3,3-三甲基二硅氧烷 反应 0.01h， 生成 甲基三氯硅烷 、 氯五甲基二硅氧烷 、 二氯二甲基硅烷 、 pentachloro-1,1,1-trimethyltrisiloxane
  参考文献：
  名称：

  1,1,1-Trimethyl-3,3,3-trichlorodisiloxane as a source and a trapping agent for silanones

  摘要：

  The pyrolysis of 1,1,1-trimethyl-3,3,3-trichlorodisiloxane (1) was studied and its mechanism involving the formation of dichloro- and dimethylsilanones was proposed. The composition of the condensate from the co-pyrolysis of siloxane 1 and hexamethyldisiloxane indicated that under the pyrolysis conditions the simplest siloxanes can be both the sources and the trapping agents of silanones.

  DOI：

  10.1007/bf01431631

文献信息

• Chernyshev, E. A.; Krasnova, T. L.; Mudrova, N. A., Journal of general chemistry of the USSR, 1992, vol. 62, # 8, p. 1502 - 1509
  作者：Chernyshev, E. A.、Krasnova, T. L.、Mudrova, N. A.、Bochkarev, V. N.

  DOI：——

  日期：——
• Chernyshev, E. A.; Mudrova, N. A.; Krasnova, T. L., Journal of general chemistry of the USSR, 1987, vol. 57, # 6, p. 1142 - 1146
  作者：Chernyshev, E. A.、Mudrova, N. A.、Krasnova, T. L.、Tarasova, T. N.、Chernyshev, A. E.

  DOI：——

  日期：——
• Chernyshev, E. A.; Krasnova, T. L.; Mudrova, N. A., Journal of general chemistry of the USSR, 1987, p. 1539 - 1543
  作者：Chernyshev, E. A.、Krasnova, T. L.、Mudrova, N. A.、Golovkin, A. V.、Kuznetsova, M. G.

  DOI：——

  日期：——
• 1,1,1-Trimethyl-3,3,3-trichlorodisiloxane as a source and a trapping agent for silanones
  作者：T. L. Krasnova、E. A. Chernyshev、A. P. Sergeev

  DOI：10.1007/bf01431631

  日期：1996.5

  The pyrolysis of 1,1,1-trimethyl-3,3,3-trichlorodisiloxane (1) was studied and its mechanism involving the formation of dichloro- and dimethylsilanones was proposed. The composition of the condensate from the co-pyrolysis of siloxane 1 and hexamethyldisiloxane indicated that under the pyrolysis conditions the simplest siloxanes can be both the sources and the trapping agents of silanones.